Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002066976> ?p ?o ?g. }
- W2002066976 endingPage "3081" @default.
- W2002066976 startingPage "3071" @default.
- W2002066976 abstract "The oxygen atom transfer reactivity (OAT) of dioxo-Mo(VI) complexes of hydrotrispyrazolyl borate (hydrotris(3,5-dimethylpyrazolyl)borate, TpMe2; hydrotris(3-isopropylpyrazol-1-yl)borate, TpiPr) with tertiary phosphines (PMe3, PMe2Ph, PEt3, PEt2Ph, PBun3, PMePh2, or PEtPh2) has been investigated. In acetonitrile, these reactions proceed via the formation of a phosphoryl intermediate complex that undergoes a solvolysis reaction. We report the synthesis and characterization of several phosphoryl complexes. The rates of formation of phosphoryl complexes and their solvation were determined by spectrophotometry. The rates of the reactions and the properties of the phosphoryl species were investigated using the Quantitative Analysis of Ligand Effect (QALE) methodology. The results show that, at least in this system, the first step of the reaction is controlled primarily by the steric factor, and in the second step, both electronic and steric factors are important. We also analyzed the effect of ligands on the reaction rate i.e., TpMe2vs. TpiPr." @default.
- W2002066976 created "2016-06-24" @default.
- W2002066976 creator A5004763246 @default.
- W2002066976 creator A5004964315 @default.
- W2002066976 creator A5050112921 @default.
- W2002066976 creator A5059700931 @default.
- W2002066976 date "2013-01-01" @default.
- W2002066976 modified "2023-10-18" @default.
- W2002066976 title "Quantitation of the ligand effect in oxo-transfer reactions of dioxo-Mo(<scp>vi</scp>) trispyrazolyl borate complexes" @default.
- W2002066976 cites W15085303 @default.
- W2002066976 cites W1965199116 @default.
- W2002066976 cites W1970725318 @default.
- W2002066976 cites W1973723982 @default.
- W2002066976 cites W1977675893 @default.
- W2002066976 cites W1978447845 @default.
- W2002066976 cites W1978498276 @default.
- W2002066976 cites W1982739004 @default.
- W2002066976 cites W1983523059 @default.
- W2002066976 cites W1984584093 @default.
- W2002066976 cites W1988557359 @default.
- W2002066976 cites W1989020464 @default.
- W2002066976 cites W1989483883 @default.
- W2002066976 cites W1991417181 @default.
- W2002066976 cites W1991968817 @default.
- W2002066976 cites W1994498587 @default.
- W2002066976 cites W2002327889 @default.
- W2002066976 cites W2002814363 @default.
- W2002066976 cites W2003781065 @default.
- W2002066976 cites W2005095656 @default.
- W2002066976 cites W2006225650 @default.
- W2002066976 cites W2006243394 @default.
- W2002066976 cites W2006984684 @default.
- W2002066976 cites W2010116681 @default.
- W2002066976 cites W2017080026 @default.
- W2002066976 cites W2017108051 @default.
- W2002066976 cites W2017939260 @default.
- W2002066976 cites W2020945967 @default.
- W2002066976 cites W2021131903 @default.
- W2002066976 cites W2024275721 @default.
- W2002066976 cites W2025169465 @default.
- W2002066976 cites W2027030362 @default.
- W2002066976 cites W2027848858 @default.
- W2002066976 cites W2028587307 @default.
- W2002066976 cites W2029292244 @default.
- W2002066976 cites W2030790509 @default.
- W2002066976 cites W2031898426 @default.
- W2002066976 cites W2035622104 @default.
- W2002066976 cites W2036649036 @default.
- W2002066976 cites W2036779081 @default.
- W2002066976 cites W2042843248 @default.
- W2002066976 cites W2047757983 @default.
- W2002066976 cites W2052055959 @default.
- W2002066976 cites W2059297033 @default.
- W2002066976 cites W2059990502 @default.
- W2002066976 cites W2062271850 @default.
- W2002066976 cites W2067999071 @default.
- W2002066976 cites W2070433577 @default.
- W2002066976 cites W2070463968 @default.
- W2002066976 cites W2074156707 @default.
- W2002066976 cites W2075015682 @default.
- W2002066976 cites W2081502054 @default.
- W2002066976 cites W2084063568 @default.
- W2002066976 cites W2089057946 @default.
- W2002066976 cites W2091702998 @default.
- W2002066976 cites W2095578829 @default.
- W2002066976 cites W2124374557 @default.
- W2002066976 cites W2126456269 @default.
- W2002066976 cites W2130118277 @default.
- W2002066976 cites W2155687033 @default.
- W2002066976 cites W2160933213 @default.
- W2002066976 cites W2313218580 @default.
- W2002066976 cites W2316686829 @default.
- W2002066976 cites W2330371700 @default.
- W2002066976 cites W2333269426 @default.
- W2002066976 cites W2403779210 @default.
- W2002066976 cites W2486094188 @default.
- W2002066976 cites W2491203026 @default.
- W2002066976 cites W2949342357 @default.
- W2002066976 cites W2950638770 @default.
- W2002066976 cites W2952484183 @default.
- W2002066976 cites W2952889337 @default.
- W2002066976 cites W4242312575 @default.
- W2002066976 cites W4245399940 @default.
- W2002066976 doi "https://doi.org/10.1039/c2dt32349d" @default.
- W2002066976 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3566299" @default.
- W2002066976 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23212540" @default.
- W2002066976 hasPublicationYear "2013" @default.
- W2002066976 type Work @default.
- W2002066976 sameAs 2002066976 @default.
- W2002066976 citedByCount "22" @default.
- W2002066976 countsByYear W20020669762013 @default.
- W2002066976 countsByYear W20020669762014 @default.
- W2002066976 countsByYear W20020669762015 @default.
- W2002066976 countsByYear W20020669762016 @default.
- W2002066976 countsByYear W20020669762017 @default.
- W2002066976 countsByYear W20020669762018 @default.
- W2002066976 countsByYear W20020669762019 @default.
- W2002066976 countsByYear W20020669762021 @default.