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- W2002073823 abstract "The hydrated complex of gramicidin A with Na+ cations was studied by FTIR spectroscopy. The water bands observed in the FTIR spectrum are identical with those obtained for the hydrated gA–Li+ complexes. In the far infrared spectrum of the gA–Na+ complex an intense continuum was found indicating large Na+ polarizability of the gA channels. This Na+ polarizability arises, similarly as in the case of the Li+ complex, due to the fast fluctuation of the Na+ ions between two water molecules and four CO groups of the gA backbone. The much smaller barriers in the six minima Na+ potentials explain the much larger mobility of the Na+ when compared with the Li+ ions. © 1999 John Wiley & Sons, Inc. Biospectroscopy 5: 284–288, 1999" @default.
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- W2002073823 date "1999-01-01" @default.
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- W2002073823 title "FTIR study of the nature of Na+ cation motion in gramicidin A" @default.
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- W2002073823 doi "https://doi.org/10.1002/(sici)1520-6343(1999)5:5<284::aid-bspy3>3.0.co;2-4" @default.
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