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- W2002074094 abstract "The mercaptolysis of the α-and β-pentaacetyl derivatives of glucopyranose and galactopyranose at 0 °C. with zinc chloride catalyst was studied. The β-pentaacetates were rapidly transformed to the corresponding ethyl tetraacetyl-1-thio-β-D-glycosides in excellent yields; however, the α-anomers were highly resistant to the mercaptolytic conditions. The results are interpreted on the basis of a participation by the C 2 -acetoxy group in the replacements at the lactol carbon atom of the β-pentaacetates with the intermediate formation of a resonance stabilized cyclic carbonium ion." @default.
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- W2002074094 date "1951-12-01" @default.
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- W2002074094 title "THE MERCAPTOLYSIS OF GLUCOSE AND GALACTOSE PENTAACETATES" @default.
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- W2002074094 doi "https://doi.org/10.1139/v51-127" @default.
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