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• W2002077834 abstract "Due to intermolecular interactions, the surface composition of mixed self-assembled monolayers often differs markedly from the solution composition. In the case of charged surfactants, large deviations from the ideality have been reported. The effect of the electrostatic interactions between charged compounds on the surface composition is examined using a simple gas lattice model, in the Bragg−Williams approximation. The interaction potential is obtained from the Debye−Hückel treatment of electrolytic solutions. The model is able to explain and reproduce the deviations observed experimentally, both qualitatively and quantitatively. The key role played by the ionic strength on the surface composition is emphasized." @default.
• W2002077834 created "2016-06-24" @default.
• W2002077834 creator A5004834295 @default.
• W2002077834 creator A5068473216 @default.
• W2002077834 date "2009-01-09" @default.
• W2002077834 modified "2023-10-16" @default.
• W2002077834 title "A Simple Model to Describe the Effect of Electrostatic Interactions on the Composition of Mixed Self-Assembled Monolayers" @default.
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• W2002077834 doi "https://doi.org/10.1021/la8033066" @default.
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• W2002077834 hasPublicationYear "2009" @default.
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