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• W2002077993 abstract "The adsorption of potassium on Pd{110} has been examined via correlated Auger electron spectroscopy, temperature programmed desorption, low-energy electron diffraction, and secondary electron emission crystal current measurements. Potassium overlayers are disordered at all coverages above 115 K. The uptake of K is readily monitored and the coverage calibrated by measuring the crystal current on adsorption below 200 K. The desorption of multilayer K is found to overlap the low-temperature first layer desorption feature and thus it is not appropriate to assume that the heat of adsorption for first layer K is considerably higher than for multilayer K in this case. Crystal current measurements at higher temperature indicate that some multilayer adsorption sites are populated before the first K layer is saturated. These results reflect the equilibrium distribution of adsorbates over the available sites, which is largely governed by the coverage-dependent differential heats of adsorption for first and second layers." @default.
• W2002077993 created "2016-06-24" @default.
• W2002077993 creator A5052301370 @default.
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• W2002077993 date "2003-12-11" @default.
• W2002077993 modified "2023-09-27" @default.
• W2002077993 title "Coverage and temperature-dependent behavior of potassium on Pd{110}" @default.
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• W2002077993 doi "https://doi.org/10.1103/physrevb.68.235406" @default.
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