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- W2002084141 abstract "Tin(IV) molybdosilicate samples were synthesized under different conditions. The most stable sample shows an ion-exchange capacity of 0.65 meq/g in the H+ form at 40°C. Its ion exchange properties were studied with the help of pH titrations, IR and X-ray spectroscopy, thermogravimetric analysis and differential thermal analysis. Tin(IV) molybdosilicate is thermally much more stable than other tin(IV)-based ion exchangers and shows a considerable increase in its ion-exchange capacity (1.2 meq/g) after drying at 800°C. The adsorption of different metal ions in water, various concentrations of nitric acid and 0.01 M ammonium nitrate was studied. Tin(IV) molybdosilicate was found to be highly selective for Th(IV). The analytical and industrial importance of this material was demonstrated by the following separations: Hg2+Zn2+, Hg2+Cd2+, Mn2+Al3+, Mn2+Ni2+, Mn2+Zn2+, Fe3+Al3+, Fe3+Zn2+ and Fe3+Cd2+. A comparison of the ion-exchange properties of this material with other tin(IV)-based ion exchangers was also carried out." @default.
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- W2002084141 date "1984-12-01" @default.
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- W2002084141 title "Synthesis and ion exchange properties of thermally stable, thorium(IV)-selective tin(IV) molybdosilicate: comparison with other tin(IV)-based ion exchangers" @default.
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- W2002084141 doi "https://doi.org/10.1016/0167-6989(84)90119-3" @default.
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