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• W2002085198 abstract "An array of random mutants of cyclohexanone monooxygenase (CHMO) from Acinetobacter sp. NCIMB 9871 was screened against a library of structurally diverse ketones for modifications in the substrate acceptance profile and stereopreference of the enzymatic Baeyer−Villiger biooxidation. While the set of mutant biocatalysts was initially evolved for the enantiocomplementary oxidation of 4-hydroxycyclohexanone, improved and/or divergent stereoselectivities were observed for several substrates. In addition, expanded substrate acceptance to facilitate biotransformation of sterically demanding ketones was found." @default.
• W2002085198 created "2016-06-24" @default.
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• W2002085198 date "2006-02-21" @default.
• W2002085198 modified "2023-10-16" @default.
• W2002085198 title "Microbial Baeyer−Villiger Oxidation: Stereopreference and Substrate Acceptance of Cyclohexanone Monooxygenase Mutants Prepared by Directed Evolution" @default.
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• W2002085198 doi "https://doi.org/10.1021/ol0601040" @default.
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