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- W2002108488 abstract "Tin-doped samples of Hg1−xSnxBa2Ca2Cu3O8+δ (hereafter symbolized as (Hg1−xSnx)-1223) with x = 0, 0.05, 0.1, 0.2, 0.4 and 0.5 have been synthesized in sealed silica tubes by the solid state reaction method. The precursor can be prepared in air. The effects of Sn doping on the formation and stability, microstructure of grain growth and critical temperature of the (Hg1−xSnx)-1223 superconductor have been investigated by X-ray diffraction, scanning electron microscopy (SEM) and electron probe microanalysis (EDS), thermogravity analysis, resistance measurements and ac susceptibility measurement techniques. Experimental results show that a small amount of Sn doped in Hg-1223 promotes the formation of the triple CuO2-layer superconducting compound. The stability of the product compounds is also enhanced. Sn doping may play a role as a nucleating centre. The Tc for Sn-doped samples (Hg1−xSnx)-1223 with x ≤ 0.1 does not notably change as compared with the pure Hg-1223 phase (about 134 K). Sn doping is favourable for synthesizing the Hg-1223 superconductor. However, further increasing of Sn doping into the sample leads to a deterioration on both Tc and the fraction of superconducting phase." @default.
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- W2002108488 date "1997-12-01" @default.
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- W2002108488 title "Effects of Sn doping in Hg1−xSnxBa2Ca2Cu2O8+δ superconductors" @default.
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- W2002108488 doi "https://doi.org/10.1016/s0921-4534(97)01776-0" @default.
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