FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002111307> ?p ?o ?g. }

• W2002111307 endingPage "49" @default.
• W2002111307 startingPage "33" @default.
• W2002111307 abstract "Fifty years ago, when this journal was founded, organometallic chemists could not have imagined that common small molecules such as dinitrogen and especially dihydrogen could function as ligands. Dihydrogen has long been vital in catalytic processes such as hydrogenation and conversions of organic compounds and is now being considered as a future energy storage medium. Dihydrogen is only useful chemically when the two strongly bound H atoms are split apart in a controlled fashion. Although metal hydrides were first well established in 1955, the structure and mechanism by which H2 binds to and undergoes cleavage on transition metals was not ascertained until even more recently in the history of inorganometallic chemistry, about 20 years after this journal was first published. The activation of dihydrogen is a fascinating saga that has slowly unfolded over the past 80+ years, as will be chronicled in this Perspective. There is a marvelous analogy between the metal-olefin π bonding model first brought to light by Dewar, Chatt, and Duncanson 60 years ago and the bonding model for side-on σ-bond coordination discovered by us 30 years ago. There are two separate pathways for H–H (and X–H σ-bond activation in general) that directly depend on the electronics of the metal σ-ligand bonding. Metal d to σ* X–H backdonation is the key to stabilizing σ-bond coordination and also is crucial to its homolytic cleavage (oxidation addition). For electrophilic complexes, particularly cationic systems with minimal backdonation, heterolytic cleavage of H2 is common and is a key reaction in industrial and biological catalysis." @default.
• W2002111307 created "2016-06-24" @default.
• W2002111307 creator A5065783859 @default.
• W2002111307 date "2014-02-01" @default.
• W2002111307 modified "2023-10-17" @default.
• W2002111307 title "Activation of dihydrogen and coordination of molecular H2 on transition metals" @default.
• W2002111307 cites W1031413567 @default.
• W2002111307 cites W1448404673 @default.
• W2002111307 cites W1518331094 @default.
• W2002111307 cites W155612545 @default.
• W2002111307 cites W1630264754 @default.
• W2002111307 cites W1963761806 @default.
• W2002111307 cites W1964774141 @default.
• W2002111307 cites W1966487193 @default.
• W2002111307 cites W1967883844 @default.
• W2002111307 cites W1969520480 @default.
• W2002111307 cites W1973398408 @default.
• W2002111307 cites W1974535808 @default.
• W2002111307 cites W1974864818 @default.
• W2002111307 cites W1975501285 @default.
• W2002111307 cites W1977236273 @default.
• W2002111307 cites W1978132389 @default.
• W2002111307 cites W1978338048 @default.
• W2002111307 cites W1979059093 @default.
• W2002111307 cites W1983607064 @default.
• W2002111307 cites W1986515064 @default.
• W2002111307 cites W1986829915 @default.
• W2002111307 cites W1987335615 @default.
• W2002111307 cites W1989727476 @default.
• W2002111307 cites W1990947180 @default.
• W2002111307 cites W1992344406 @default.
• W2002111307 cites W1994567008 @default.
• W2002111307 cites W1995944743 @default.
• W2002111307 cites W1997264071 @default.
• W2002111307 cites W1997538210 @default.
• W2002111307 cites W2000221096 @default.
• W2002111307 cites W2000252268 @default.
• W2002111307 cites W2002010246 @default.
• W2002111307 cites W2004242300 @default.
• W2002111307 cites W2004738657 @default.
• W2002111307 cites W2005563235 @default.
• W2002111307 cites W2006130370 @default.
• W2002111307 cites W2007659040 @default.
• W2002111307 cites W2007676802 @default.
• W2002111307 cites W2008049933 @default.
• W2002111307 cites W2010073213 @default.
• W2002111307 cites W2010728306 @default.
• W2002111307 cites W2011344922 @default.
• W2002111307 cites W2011424986 @default.
• W2002111307 cites W2012543217 @default.
• W2002111307 cites W2015109253 @default.
• W2002111307 cites W2015784886 @default.
• W2002111307 cites W2015829181 @default.
• W2002111307 cites W2018421455 @default.
• W2002111307 cites W2018506301 @default.
• W2002111307 cites W2019437299 @default.
• W2002111307 cites W2019480764 @default.
• W2002111307 cites W2020414767 @default.
• W2002111307 cites W2021352061 @default.
• W2002111307 cites W2023040943 @default.
• W2002111307 cites W2026572123 @default.
• W2002111307 cites W2026723095 @default.
• W2002111307 cites W2027821954 @default.
• W2002111307 cites W2029225284 @default.
• W2002111307 cites W2031587962 @default.
• W2002111307 cites W2036146015 @default.
• W2002111307 cites W2037612742 @default.
• W2002111307 cites W2037707668 @default.
• W2002111307 cites W2038071113 @default.
• W2002111307 cites W2038093666 @default.
• W2002111307 cites W2039691813 @default.
• W2002111307 cites W2040299058 @default.
• W2002111307 cites W2040371083 @default.
• W2002111307 cites W2041086195 @default.
• W2002111307 cites W2041606536 @default.
• W2002111307 cites W2041706198 @default.
• W2002111307 cites W2043035912 @default.
• W2002111307 cites W2045041784 @default.
• W2002111307 cites W2045411127 @default.
• W2002111307 cites W2049439497 @default.
• W2002111307 cites W2049951993 @default.
• W2002111307 cites W2050398995 @default.
• W2002111307 cites W2051867108 @default.
• W2002111307 cites W2051985524 @default.
• W2002111307 cites W2058503266 @default.
• W2002111307 cites W2059530602 @default.
• W2002111307 cites W2059557791 @default.
• W2002111307 cites W2060832403 @default.
• W2002111307 cites W2062118495 @default.
• W2002111307 cites W2062345835 @default.
• W2002111307 cites W2062406894 @default.
• W2002111307 cites W2066050267 @default.
• W2002111307 cites W2070760110 @default.
• W2002111307 cites W2071258936 @default.
• W2002111307 cites W2071946958 @default.
• W2002111307 cites W2072760145 @default.
• W2002111307 cites W2074216327 @default.
• W2002111307 cites W2075530020 @default.

• next