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- W2002113831 abstract "Exposure of dihydropyridinone 1 to the arylbismuth(V) reagent (p-F-Ph)3BiCl2 in the presence of substoichiometric quantities of tributylphosphine (10 mol %) results in aryl transfer to the transiently generated (β-phosphonio)enolate to provide the α-arylated enone 2. This transformation, which represents a regiochemical complement to the Mizoroki–Heck arylation, is used strategically in concise formal and enantioselective total syntheses of the blockbuster antidepressant (−)-paroxetine (PAXIL)." @default.
- W2002113831 created "2016-06-24" @default.
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- W2002113831 date "2006-11-01" @default.
- W2002113831 modified "2023-10-18" @default.
- W2002113831 title "Enantioselective total and formal syntheses of paroxetine (PAXIL) via phosphine-catalyzed enone α-arylation using arylbismuth(V) reagents: a regiochemical complement to Heck arylation" @default.
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- W2002113831 doi "https://doi.org/10.1016/j.tet.2006.05.092" @default.
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