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• W2002114530 abstract "The solid solution of the cubic Laves phase derivative α-ZrCr2Dx undergoes a structural phase transition at low temperature that leads to a novel type of deuterium atom ordering. Neutron powder diffraction at 50 and 2 K reveals a monoclinic structure of composition ZrCr2D0.66 (space group P21/n, Z=8; a=894.11(3) pm, b=513.72(2) pm, c=890.50(4), β=109.563(3)° at 2 K) in which deuterium occupies four (out of 24) sorts of [Zr2Cr2] type interstices with occupancies in the range 23–40%. The ordering differs from that in the more deuterium rich monoclinic low temperature structure of α′-ZrCr2D3.8 (space group C2/c) and leads to the lowest deuterium-to-metal ratio known among Laves phase derivative structures undergoing order–disorder transitions. A list of known compositions for ordered (or partially ordered) cubic Laves phase hydride derivative structures is given." @default.
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• W2002114530 date "2001-08-01" @default.
• W2002114530 modified "2023-10-14" @default.
• W2002114530 title "Low-temperature deuterium ordering in the cubic Laves phase derivative α-ZrCr2D0.66" @default.
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• W2002114530 doi "https://doi.org/10.1016/s0925-8388(01)01565-1" @default.
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