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- W2002132300 abstract "Matrix effects on the frequencies of i.r. vibrations of hydroxy and deuteroxy groups in CH3OH and D2O have been studied. Band shifts, Δν, show a linear dependence on √Tc(where Tc is the critical temperature) of the substance comprising the matrix, as a measure of the intermolecular potential. Within a homologous series Δν is more sensitive to hydrogen bonding than to van der Waals interactions. This implies that the application of the Badger–Bauer rule to hydrogen-bonded systems must take non-polar solvents as frequency standard and not the vapour state." @default.
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- W2002132300 date "1984-01-01" @default.
- W2002132300 modified "2023-09-26" @default.
- W2002132300 title "Matrix effects on hydroxy-group vibrational frequencies caused by weak intermolecular interactions" @default.
- W2002132300 doi "https://doi.org/10.1039/f29848000579" @default.
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