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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002138370> ?p ?o ?g. }

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• W2002138370 abstract "We report the discovery of a supramolecular interaction (anion-π and charge/electron transfer, CT/ET) involving fluoride ion and π-electron deficient colorless naphthalene diimide (NDI) receptors. Strong electronic interactions between lone-pair electrons of F(-) ion and π*-orbitals of the NDI unit lead to an unprecedented F(-)→NDI ET event, which produces an orange colored NDI(•-) radical anion. Further reduction of NDI(•-) by another F(-) ion produces a pink colored NDI(2-) dianion, rendering NDI a colorimetric F(-) sensor. Preorganization of two NDI units in overlapping positions using folded linkers improves their selectivity and sensitivity for the F(-) ion significantly, allowing F(-) detection at nM concentration in 85:15 DMSO/H(2)O solutions." @default.
• W2002138370 created "2016-06-24" @default.
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• W2002138370 date "2010-11-29" @default.
• W2002138370 modified "2023-10-18" @default.
• W2002138370 title "Fluoride Ion Sensing by an Anion−π Interaction" @default.
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• W2002138370 doi "https://doi.org/10.1021/ja107382x" @default.
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