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- W2002157622 abstract "Abstract A new cyanocarbon is formed in a discharge of dicyanoacetylene (NC 4 N) and studied in rare gas matrices through its visible absorption, laser-induced fluorescence, and laser excitation spectra. The spectrum, with origin at 22737 cm −1 in an argon matrix, exhibits strong progressions in a vibrational mode around 2000 cm −1 , typical for a linear molecule with multiple bonds. Isotopic studies suggest that the carrier contains two equivalent nitrogen atoms and probably five carbons. They also point to a centro-symmetric molecule with two equivalent carbon atom pairs. Given this information, we assign the carrier of this spectrum tentatively to a linear cumulenic NC 5 N or CNC 3 NC. Chemical evidence suggests it may be formed by the reaction of C atoms with NC 4 N or its isomer NC 3 NC." @default.
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- W2002157622 date "1994-06-01" @default.
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- W2002157622 title "Tentative identification of C5N2 in rare gas matrices" @default.
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- W2002157622 doi "https://doi.org/10.1016/0301-0104(94)00096-4" @default.
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