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- W2002158826 abstract "The effective rotational Hamiltonian for the stretching modes of H<SUB>2</SUB>X molecules have been analyzed on the base of the two conceptions: site-symmetry and linked groupings of vibrational rotational interactions. The site-symmetry of the effective Hamiltonian for the region of (v<SUB>1</SUB>, v<SUB>3</SUB>) dyad of H<SUB>2</SUB>X molecules at the condition m<SUB>H</SUB> << m<SUB>x</SUB> is reduced to C<SUB>s</SUB> symmetry, as compared with C<SUB>2</SUB>V symmetry of the initial Hamiltonian. For the first time for H<SUB>2</SUB>X molecule with strong Coriolis-type accidental resonance it had been shown that the parameters of effective Hamiltonian depend on groupings of vibrational- rotational interactions. This dependence from weak via middle to strong resonances has the trend to decrease. For H<SUB>2</SUB>S molecule at the local mode limit, the effective Hamiltonian for Coriolis-type resonance don't depend on the groupings of initial Hamiltonian expansions. Two ways of experimental energy levels assignment for some vibrational polyads of H<SUB>2</SUB>S molecule, based on the symmetry reduction conception have been presented." @default.
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- W2002158826 date "1999-01-13" @default.
- W2002158826 modified "2023-09-23" @default.
- W2002158826 title "<title>Site symmetry and effective Hamiltonians for H<formula><inf><roman>2</roman></inf></formula>X molecules in the local mode limit</title>" @default.
- W2002158826 doi "https://doi.org/10.1117/12.336992" @default.
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