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- W2002167922 abstract "Abstract Europium-doped NaY(PO 3 ) 4 single crystals have been synthesized by the flux method with sizes around 1 mm 3 . The unit cell parameters at room temperature refined by X-ray powder diffraction are a =7.1510(4) A; b =13.0070(8) A; c =9.6973(2) A; β =90.606(3)°, Z =4 with the space group P 2 1 / n in monoclinic system. The present single crystals have a needle shape, they are elongated along the a crystallographic direction, and their size is in the 500 μm–1 mm range. The linear thermal expansion tensor parameters were determined, being the maximum value along the b direction, 16.1×10 −6 K −1 and the minimum along the a direction being 11.7×10 −6 K −1 . The IR vibration modes attributed to the group P–O are consistent with the crystallographic data concerning the chain aspect of the phosphate anion. This material melts incongruently at 1141 K. Intense visible emissions attributed to Eu 3+ 5 D 0 → 7 F 1 , 5 D 0 → 7 F 2 and 5 D 0 → 7 F 4 , electronic transitions have been observed after pumping at 355 nm at room temperature." @default.
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- W2002167922 date "2009-09-01" @default.
- W2002167922 modified "2023-09-27" @default.
- W2002167922 title "Crystal growth, characterization and spectroscopic study of europium-doped NaY(PO3)4" @default.
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- W2002167922 doi "https://doi.org/10.1016/j.jcrysgro.2009.05.030" @default.
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