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- W2002168036 abstract "The possibilities of using observable cation equilibria to obtain evidence concerning C—H hyperconjugation are discussed. The experimental approach of this paper, using tetraalkylcyclopentenyl cation equilibria, is to vary the structure of the normal alkyl series in such a way that the hypothetical C—H hyperconjugative ability remains constant for a given series while the steric bulk of the groups changes. In fact, the observed equilibrium changes are minimal. Other experiments have been performed to measure both the effect of solvents on the equilibrium constants and the rate of the equilibration reaction. Still other experiments were designed to test the ability of H vs. CH 3 in stabilizing alkyl cations and a value of ≥ 4.6 kcal/mol favoring CH 3 has been found. Finally, the possibility of using structurally similar cation and anion equilibria to cancel out steric effects in these equilibria is discussed." @default.
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- W2002168036 date "1972-11-01" @default.
- W2002168036 modified "2023-09-28" @default.
- W2002168036 title "Equilibria Studies on Tetraalkylcyclopentenyl Cations. A Steric Origin for a Baker–Nathan Order?" @default.
- W2002168036 doi "https://doi.org/10.1139/v72-567" @default.
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