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- W2002186817 abstract "Abstract The electrochemical behaviour of sulphur dioxide in sulphuric acid solutions at a platinum rde is characterized. Cycling the potential in these solutions between about −0.10 and 1.2 V sce results in activation of the electrode so that diffusion-controlled SO 2 oxidation currents can be observed in the double layer region of platinum. Without activation, SO 2 oxidation proceeds noticeably only in the potenial region of surface oxide formation. Evidence is presented which indicates that activation results from formation of a catalytic layer of sulphur species. The catalytic activity of this layer decays with time in the course of SO 2 oxidation. The formation of sulphur oxides through oxidation of adsorbed sulphur and the formation of platinum oxides complicate the voltammetric behaviour of the system." @default.
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- W2002186817 date "1983-08-01" @default.
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- W2002186817 title "The activated electro-oxidation of sulphur dioxide on smooth platinum" @default.
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- W2002186817 doi "https://doi.org/10.1016/0013-4686(83)80008-5" @default.
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