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- W2002191704 abstract "Eine Reihe offenkettiger, cyclischer und aromatischer Dicarbonylverbindungen werden mit Methylenbromid/Butyllithium zu den Bis-epoxiden 2,3,5,6,8–11 und 14 umgesetzt. In einigen Fällen werden daneben die Mono-epoxide 1,7 und 13 erhalten. Sterisch stark gehinderte Carbonylverbindungen ergeben nur das Mono-epoxid (z. B. Bipivaloyl → 4). Synthesis of Bis-epoxides from Dicarbonyl Compounds and Methylene Bromide/Butyllithium Several acylic, cyclic, and aromatic dicarbonyl compounds react with methylene bromide/butyllithium to give the bis-epoxides 2,3,5,6,8–11, and 14. In some cases the mono-epoxides 1,7, and 13 are also obtained. Sterically strongly hindered carbonyl compounds yield the mono-epoxides only (e. g. bipivaloyl → 4)." @default.
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- W2002191704 date "1975-07-01" @default.
- W2002191704 modified "2023-10-03" @default.
- W2002191704 title "Synthese von Bis‐epoxiden aus Dicarbonylverbindungen und Methylenbromid/Butyllithium" @default.
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- W2002191704 doi "https://doi.org/10.1002/cber.19751080726" @default.
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