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• W2002192489 abstract "Abstract Summary: The combination of enzymatic polymerization with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one‐pot enzymatic procedure by using 2‐hydroxyethyl α ‐bromoisobutyrate as a bifunctional initiator. A polymerizable end group was introduced by subsequent in situ enzymatic acrylation with vinyl acrylate. Branched polymers were obtained by subsequent atom transfer radical polymerization (ATRP). Enzymatic synthesis of heterotelechelic macromonomers and subsequent self condensing vinyl polymerization by ATRP. image Enzymatic synthesis of heterotelechelic macromonomers and subsequent self condensing vinyl polymerization by ATRP." @default.
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• W2002192489 date "2005-04-22" @default.
• W2002192489 modified "2023-10-17" @default.
• W2002192489 title "Chemoenzymatic Synthesis of Branched Polymers" @default.
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• W2002192489 doi "https://doi.org/10.1002/marc.200500011" @default.
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