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- W2002192718 abstract "Abstract LiFePO 4 –silicon composites were fabricated by using a solid-state method for applying positive electrodes in lithium ion batteries. The LiFePO 4 –silicon composites were characterized with X-ray diffraction and field emission scanning electron microscopy. Their electrochemical properties were investigated with cyclic voltammetry, electrochemical impedance spectroscopy, and charge–discharge tests. The added silicon not only suppressed the surface corrosion caused by the decreasing H + concentration in the electrolyte, but it also acted as a barrier between the LiFePO 4 particles and LiPF 6 electrolyte, thereby preventing the dissolution of Fe 2+ in the electrode and enhancing the electrolyte/active material interactions. This resulted in improved lithium-ion transfer kinetics and excellent positive electrode performance, especially at high current densities and different operating temperatures (0, 25, and 50 °C). At 25 °C, the LiFePO 4 composite containing 2 wt% of silicon delivered the best electrochemical performance with a lithium-ion diffusion coefficient of 1.81×10 −9 cm 2 s −1 , a specific discharge capacity of 143 mA h g −1 for the initial cycle, and a capacity retention of 98% after 100 cycles. In contrast, the corresponding values for the pure LiFePO 4 were 1.19×10 −11 cm 2 s −1 , 115 mA h g −1 , and a capacity retention of 76% after 100 cycles, respectively." @default.
- W2002192718 created "2016-06-24" @default.
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- W2002192718 date "2015-09-01" @default.
- W2002192718 modified "2023-09-27" @default.
- W2002192718 title "Enhanced electrochemical properties of LiFePO4–silicon composites as positive electrode materials fabricated using a solid-state method" @default.
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- W2002192718 doi "https://doi.org/10.1016/j.ceramint.2015.04.002" @default.
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