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- W2002195817 abstract "The deuteron spin–lattice relaxation times (T1) of adamantane-d16, tris(3-deutero-2,4-pentadionato) aluminum, α,α-dideuterotetraethylammonium iodide, and α,α-dideuterotetrabutylammonium iodide in several solvents are studied as functions of temperature. The rotational correlation times (τc) for the solute molecules were obtained from the T1 data. The results were analyzed in terms of a dimensionless parameter κ, which is the ratio between experimental τc and the value of τc calculated from the Debye–BPP equation. It seems that for molecules with small κ (slip boundary condition), the value of κ increases with the increase of temperature and for molecules with κ closer to one (stick boundary condition), the value of κ decreases with the increase of temperature." @default.
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- W2002195817 date "1978-07-01" @default.
- W2002195817 modified "2023-10-17" @default.
- W2002195817 title "Molecular motions in liquid. II. Deuteron relaxation study of the rotation of highly symmetrical molecules in solutions" @default.
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- W2002195817 doi "https://doi.org/10.1063/1.436376" @default.
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