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- W2002197248 abstract "The present work is the first report of using a FeIII dimeric porphyrin as an active and efficient catalyst for the oxidative desulfurization of a multicomponent oil formed by the most refractory sulfur compounds in fuels (dibenzothiophene, DBT, 1-benzothiophene, 1-BT, and 4,6-dimethyldibenzothiophene, 4,6-DMDBT), using the biphasic system model oil/extraction solvent. The binuclear μ-oxodiiron(III) complex of meso-tetrakis(pentafluorophenyl)porphyrin μ-O(FeTPFPP)2, was synthesized and characterized by UV/Vis spectroscopy, mass spectrometry and single-crystal X-ray diffraction. μ-O(FeTPFPP)2 was shown to achieve a complete desulfurization after 2 h when acetonitrile and methanol were used as extraction solvents, in the presence of a residual amount of H2O2 as oxidant, at room temperature. The catalytic efficiency of the porphyrin was evaluated for each refractory sulfur compound following the order 1-BT > DBT > 4,6-DMDBT. Surprisingly, the porphyrin presents a remarkable catalytic performance for the desulfurization of 1-BT when compared with other catalysts already reported in the literature. Furthermore, the extracting phase containing the porphyrin could be reused in consecutive desulfurization cycles." @default.
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- W2002197248 date "2014-05-01" @default.
- W2002197248 modified "2023-10-02" @default.
- W2002197248 title "An efficient eco-sustainable oxidative desulfurization process using μ-oxo-bridged Fe(III) complex of meso-tetrakis(pentafluorophenyl)porphyrin" @default.
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- W2002197248 doi "https://doi.org/10.1016/j.apcata.2014.04.002" @default.
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