FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002199493> ?p ?o ?g. }

• W2002199493 abstract "The sum of the rate constants for solvolysis and scrambling of carbon bridging and nonbridging oxygen-18 at 4-MeC(6)H(4)CH(CF(3))OS((18)O(2))Tos in 50/50 (v/v) trifluoroethanol/water, (k(solv) + k(iso)) = 5.4 × 10(-6) s(-1), is 50% larger than k(solv) = 3.6 × 10(-6) for the simple solvolysis reaction of the sulfonate ester. This shows that the ion pair intermediate of solvolysis undergoes significant internal return to form reactant. These data give a value of k(-1) = 1.7 × 10(10) s(-1) for internal return of the carbocation-anion pair to the substrate. This rate constant is larger than the value of k(-1) = 7 × 10(9) s(-1) reported for internal return of an ion pair between the 1-(4-methylphenyl)ethyl carbocation and pentafluorobenzoate anion to the neutral ester (4-MeC(6)H(4)CH(CH(3))O(2)CC(6)F(5)) in the same solvent. The partitioning of ion pairs to the 1-(4-methylphenyl)ethyl carbocation and to the highly destabilized 1-(4-methylphenyl)2,2,2-trifluoroethyl carbocation is compared and contrasted." @default.
• W2002199493 created "2016-06-24" @default.
• W2002199493 creator A5036032372 @default.
• W2002199493 creator A5053516288 @default.
• W2002199493 creator A5066402611 @default.
• W2002199493 date "2010-01-13" @default.
• W2002199493 modified "2023-09-29" @default.
• W2002199493 title "Dynamics for reactions of ion pairs in aqueous solution: reactivity of tosylate anion ion paired with the highly destabilized 1-(4-methylphenyl)-2,2,2-trifluoroethyl carbocation" @default.
• W2002199493 cites W1963688013 @default.
• W2002199493 cites W1967750525 @default.
• W2002199493 cites W1976596763 @default.
• W2002199493 cites W1978201305 @default.
• W2002199493 cites W1985659948 @default.
• W2002199493 cites W1997799969 @default.
• W2002199493 cites W2015086979 @default.
• W2002199493 cites W2021049137 @default.
• W2002199493 cites W2024773288 @default.
• W2002199493 cites W2024788272 @default.
• W2002199493 cites W2035679715 @default.
• W2002199493 cites W2046477670 @default.
• W2002199493 cites W2048992790 @default.
• W2002199493 cites W2061685797 @default.
• W2002199493 cites W2063800957 @default.
• W2002199493 cites W2064743989 @default.
• W2002199493 cites W2065582985 @default.
• W2002199493 cites W2077431430 @default.
• W2002199493 cites W2081905824 @default.
• W2002199493 cites W2088744845 @default.
• W2002199493 cites W2126215829 @default.
• W2002199493 cites W2133766002 @default.
• W2002199493 cites W2158062292 @default.
• W2002199493 cites W2949395513 @default.
• W2002199493 cites W2950491254 @default.
• W2002199493 cites W4246441921 @default.
• W2002199493 doi "https://doi.org/10.1002/poc.1642" @default.
• W2002199493 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2963475" @default.
• W2002199493 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21031146" @default.
• W2002199493 hasPublicationYear "2010" @default.
• W2002199493 type Work @default.
• W2002199493 sameAs 2002199493 @default.
• W2002199493 citedByCount "9" @default.
• W2002199493 countsByYear W20021994932012 @default.
• W2002199493 countsByYear W20021994932013 @default.
• W2002199493 countsByYear W20021994932015 @default.
• W2002199493 countsByYear W20021994932016 @default.
• W2002199493 countsByYear W20021994932017 @default.
• W2002199493 crossrefType "journal-article" @default.
• W2002199493 hasAuthorship W2002199493A5036032372 @default.
• W2002199493 hasAuthorship W2002199493A5053516288 @default.
• W2002199493 hasAuthorship W2002199493A5066402611 @default.
• W2002199493 hasBestOaLocation W20021994932 @default.
• W2002199493 hasConcept C109057382 @default.
• W2002199493 hasConcept C121332964 @default.
• W2002199493 hasConcept C145148216 @default.
• W2002199493 hasConcept C147789679 @default.
• W2002199493 hasConcept C148898269 @default.
• W2002199493 hasConcept C155647269 @default.
• W2002199493 hasConcept C178790620 @default.
• W2002199493 hasConcept C184651966 @default.
• W2002199493 hasConcept C185592680 @default.
• W2002199493 hasConcept C2779293432 @default.
• W2002199493 hasConcept C2780471494 @default.
• W2002199493 hasConcept C62520636 @default.
• W2002199493 hasConcept C75473681 @default.
• W2002199493 hasConcept C93391505 @default.
• W2002199493 hasConcept C94412978 @default.
• W2002199493 hasConceptScore W2002199493C109057382 @default.
• W2002199493 hasConceptScore W2002199493C121332964 @default.
• W2002199493 hasConceptScore W2002199493C145148216 @default.
• W2002199493 hasConceptScore W2002199493C147789679 @default.
• W2002199493 hasConceptScore W2002199493C148898269 @default.
• W2002199493 hasConceptScore W2002199493C155647269 @default.
• W2002199493 hasConceptScore W2002199493C178790620 @default.
• W2002199493 hasConceptScore W2002199493C184651966 @default.
• W2002199493 hasConceptScore W2002199493C185592680 @default.
• W2002199493 hasConceptScore W2002199493C2779293432 @default.
• W2002199493 hasConceptScore W2002199493C2780471494 @default.
• W2002199493 hasConceptScore W2002199493C62520636 @default.
• W2002199493 hasConceptScore W2002199493C75473681 @default.
• W2002199493 hasConceptScore W2002199493C93391505 @default.
• W2002199493 hasConceptScore W2002199493C94412978 @default.
• W2002199493 hasFunder F4320332161 @default.
• W2002199493 hasLocation W20021994931 @default.
• W2002199493 hasLocation W20021994932 @default.
• W2002199493 hasLocation W20021994933 @default.
• W2002199493 hasLocation W20021994934 @default.
• W2002199493 hasOpenAccess W2002199493 @default.
• W2002199493 hasPrimaryLocation W20021994931 @default.
• W2002199493 hasRelatedWork W1909312968 @default.
• W2002199493 hasRelatedWork W1987469384 @default.
• W2002199493 hasRelatedWork W2004441690 @default.
• W2002199493 hasRelatedWork W2005748930 @default.
• W2002199493 hasRelatedWork W2009863590 @default.
• W2002199493 hasRelatedWork W2013950963 @default.
• W2002199493 hasRelatedWork W2018572404 @default.
• W2002199493 hasRelatedWork W2020955217 @default.
• W2002199493 hasRelatedWork W2021745550 @default.
• W2002199493 hasRelatedWork W2024773288 @default.
• W2002199493 hasRelatedWork W2064125529 @default.
• W2002199493 hasRelatedWork W2082823840 @default.

• next