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- W2002242592 abstract "β-Pinene and epichlorohydrin (ECH) have been copolymerized cationically using BF3(C2H5)2O and SnCl4 as catalysts. Polymerizations were carried out at −80°C in methylenechloride. Monomer reactivity ratios were determined in both catalysts which were r1(ECH) = 1.06 ± 0.15 and r2 (β-pinene) = 0.32 ± 0.08 in BF3(C2H5)2O and r1(ECH) = 0.33 ± 0.11 and r2(β-pinene) = 2.03 ± 0.44 in SnCl4. Copolymers of different composition were soluble in acetone and insoluble in methanol. This characteristic was taken to indicate that the polymeric products were real copolymers and not a mixture of two homopolymers of epichlorohydrin and β-pinene." @default.
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- W2002242592 date "1981-06-01" @default.
- W2002242592 modified "2023-09-25" @default.
- W2002242592 title "Cationic copolymerization of β-pinene and epichlorohydrin" @default.
- W2002242592 doi "https://doi.org/10.1002/pol.1981.170190624" @default.
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