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- W2002244162 abstract "The (S)-selective hydroxynitrile lyase from Hevea brasiliensis (HbHNL) catalyzes the trans-cyanohydrin reaction (transcyanation). The equilibrium of this two-step reaction sequence is not favorable unless a large excess of acetone cyanohydrin (1) is used. Therefore, the coupling of this reaction with a follow-up reaction was investigated. It was established that the trans-cyanohydrin reaction could be performed in organic media, making it possible to couple it with a lipase-catalyzed acylation. Candida antarctica lipase B (CAL-B) shows a high selectivity (E=100) for (S)-mandelonitrile (4) and is, therefore, the ideal candidate for this type of multi-step one-pot reaction." @default.
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- W2002244162 date "2001-01-01" @default.
- W2002244162 modified "2023-10-13" @default.
- W2002244162 title "Enzymatic formation and esterification of (S)-mandelonitrile" @default.
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- W2002244162 doi "https://doi.org/10.1016/s1381-1177(00)00061-8" @default.
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