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- W2002244369 abstract "Radical groups, tert-butylnitroxide, nitronyl nitroxide, and 2,6-di-tert-butylphenoxyl, were introduced at the 3-position of thiophene, and the thiophene derivatives were then polymerized to yield poly(3-radical-substituted thiophene)s. The acetoxyphenyl-substituted thiophene gave regioregular poly(3-phenol-substituted thiophene) via oxidative polymerization with ferric chloride at low temperature, while the polymerization of the amine-substituted thiophenes did not proceed with any oxidizing agents under any reaction conditions. The phenoxyl-substituted polyradicals, 7 and 8, with spin concentrations of 0.30 and 0.25, respectively, displayed S values of 2/2 to 3/2 and 2/2, respectively, indicating an intramolecular ferromagnetic spin-coupling through the polythiophene backbone. The polyradicals, 7 and 8, themselves and the polyradical doped with iodine showed an electrical conductivity of 10−5 and 10−2∼−1 S cm−1, respectively." @default.
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- W2002244369 date "2001-05-01" @default.
- W2002244369 modified "2023-09-23" @default.
- W2002244369 title "Magnetic and electrical properties of poly(3-radical-substituted thiophene)s" @default.
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- W2002244369 doi "https://doi.org/10.1016/s0277-5387(01)00588-5" @default.
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