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- W2002255412 abstract "Hydrodechlorination (HDC) of CCl4 to CHCl3 is an economically and environmentally attractive alternative for CCl4 disposal. Commercially available 0.3 wt% egg-shell Pt/Al2O3 pellet catalysts from several catalyst vendors were evaluated for CCl4 HDC. In all cases, the catalysts were rapidly deactivated during reaction at 90°C; the CCl4 conversion dropped from 90% to 2% within an hour. A remarkably durable catalyst was obtained by treating the as-received commercial Pt/Al2O3 catalyst with a solution of NH4Cl. The treated catalyst showed excellent CCl4 HDC performance for over 2000 h without deactivation. Treatment with NH4Cl resulted in an increased Pt particle size, which is crucial for a Pt catalyst to resist HCl poisoning." @default.
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- W2002255412 date "1998-11-01" @default.
- W2002255412 modified "2023-10-12" @default.
- W2002255412 title "Genesis of durable catalyst for selective hydrodechlorination of CCl4 to CHCl3" @default.
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- W2002255412 doi "https://doi.org/10.1016/s0926-860x(98)00150-1" @default.
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