FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002272065> ?p ?o ?g. }

• W2002272065 endingPage "297" @default.
• W2002272065 startingPage "291" @default.
• W2002272065 abstract "Selectivities for skeletal isomerizations of n-butane and n-pentane catalyzed by typical solid acids such as Cs2.5H0.5PW12O40 (Cs2.5), SO42−/ZrO2, WO3/ZrO2, and H-ZSM-5 and their Pt-promoted catalysts were compared. High selectivities for n-butane and low selectivity for n-pentane were observed over Cs2.5 and SO42−/ZrO2, while H-ZSM-5 was much less selective, and WO3/ZrO2 was highly selective for both reactions. The Pt-promoted solid acids were usually selective for these reactions in the presence of H2 except for Pt-H-ZSM-5 for n-butane isomerization. Both the acid strength and pore structure would be factors influencing the selectivity. Mechanism of skeletal isomerization of n-butane was investigated by using 1,4-13C2-n-butane over Cs2.5 and Pt–Cs2.5. It was concluded that n-butane isomerization proceeded mainly via monomolecular pathway with intramolecular rearrangement on Pt–Cs2.5, while it occurred through bimolecular pathway with intermolecular rearrangement on Cs2.5. The higher selectivity on Pt–Cs2.5 would be brought about by the monomolecular mechanism. In the skeletal isomerization of cyclohexane, Pt–Cs2.5/SiO2 was highly active and selective, while Pt–Cs2.5 was less selective. Control in the acid strength of Cs2.5 by the supporting would be responsible for the high selectivity." @default.
• W2002272065 created "2016-06-24" @default.
• W2002272065 creator A5026095256 @default.
• W2002272065 creator A5029342738 @default.
• W2002272065 creator A5038337633 @default.
• W2002272065 creator A5043007031 @default.
• W2002272065 creator A5050253224 @default.
• W2002272065 creator A5059144047 @default.
• W2002272065 date "2002-06-01" @default.
• W2002272065 modified "2023-10-17" @default.
• W2002272065 title "Selectivity and mechanism for skeletal isomerization of alkanes over typical solid acids and their Pt-promoted catalysts" @default.
• W2002272065 cites W1533667554 @default.
• W2002272065 cites W1966329819 @default.
• W2002272065 cites W1968954964 @default.
• W2002272065 cites W1975018536 @default.
• W2002272065 cites W1975552736 @default.
• W2002272065 cites W1987333078 @default.
• W2002272065 cites W1988687618 @default.
• W2002272065 cites W1991213244 @default.
• W2002272065 cites W1993411495 @default.
• W2002272065 cites W1996793620 @default.
• W2002272065 cites W1999728142 @default.
• W2002272065 cites W2000849123 @default.
• W2002272065 cites W2003948836 @default.
• W2002272065 cites W2010140370 @default.
• W2002272065 cites W2010534272 @default.
• W2002272065 cites W2023855014 @default.
• W2002272065 cites W2025360513 @default.
• W2002272065 cites W2031047197 @default.
• W2002272065 cites W2034894589 @default.
• W2002272065 cites W2046437442 @default.
• W2002272065 cites W2050409912 @default.
• W2002272065 cites W2064473740 @default.
• W2002272065 cites W2066308883 @default.
• W2002272065 cites W2070861566 @default.
• W2002272065 cites W2070948767 @default.
• W2002272065 cites W2087140004 @default.
• W2002272065 cites W2134179892 @default.
• W2002272065 cites W2167189907 @default.
• W2002272065 cites W2257149915 @default.
• W2002272065 cites W23892019 @default.
• W2002272065 cites W372355815 @default.
• W2002272065 doi "https://doi.org/10.1016/s0920-5861(02)00031-7" @default.
• W2002272065 hasPublicationYear "2002" @default.
• W2002272065 type Work @default.
• W2002272065 sameAs 2002272065 @default.
• W2002272065 citedByCount "36" @default.
• W2002272065 countsByYear W20022720652012 @default.
• W2002272065 countsByYear W20022720652013 @default.
• W2002272065 countsByYear W20022720652015 @default.
• W2002272065 countsByYear W20022720652016 @default.
• W2002272065 countsByYear W20022720652017 @default.
• W2002272065 countsByYear W20022720652018 @default.
• W2002272065 countsByYear W20022720652019 @default.
• W2002272065 countsByYear W20022720652020 @default.
• W2002272065 countsByYear W20022720652021 @default.
• W2002272065 countsByYear W20022720652022 @default.
• W2002272065 countsByYear W20022720652023 @default.
• W2002272065 crossrefType "journal-article" @default.
• W2002272065 hasAuthorship W2002272065A5026095256 @default.
• W2002272065 hasAuthorship W2002272065A5029342738 @default.
• W2002272065 hasAuthorship W2002272065A5038337633 @default.
• W2002272065 hasAuthorship W2002272065A5043007031 @default.
• W2002272065 hasAuthorship W2002272065A5050253224 @default.
• W2002272065 hasAuthorship W2002272065A5059144047 @default.
• W2002272065 hasConcept C118792377 @default.
• W2002272065 hasConcept C126661725 @default.
• W2002272065 hasConcept C155647269 @default.
• W2002272065 hasConcept C161790260 @default.
• W2002272065 hasConcept C178790620 @default.
• W2002272065 hasConcept C185592680 @default.
• W2002272065 hasConcept C2777589835 @default.
• W2002272065 hasConcept C2778077586 @default.
• W2002272065 hasConcept C2778237882 @default.
• W2002272065 hasConcept C2778717364 @default.
• W2002272065 hasConcept C2781047139 @default.
• W2002272065 hasConcept C71240020 @default.
• W2002272065 hasConcept C75079739 @default.
• W2002272065 hasConcept C75473681 @default.
• W2002272065 hasConceptScore W2002272065C118792377 @default.
• W2002272065 hasConceptScore W2002272065C126661725 @default.
• W2002272065 hasConceptScore W2002272065C155647269 @default.
• W2002272065 hasConceptScore W2002272065C161790260 @default.
• W2002272065 hasConceptScore W2002272065C178790620 @default.
• W2002272065 hasConceptScore W2002272065C185592680 @default.
• W2002272065 hasConceptScore W2002272065C2777589835 @default.
• W2002272065 hasConceptScore W2002272065C2778077586 @default.
• W2002272065 hasConceptScore W2002272065C2778237882 @default.
• W2002272065 hasConceptScore W2002272065C2778717364 @default.
• W2002272065 hasConceptScore W2002272065C2781047139 @default.
• W2002272065 hasConceptScore W2002272065C71240020 @default.
• W2002272065 hasConceptScore W2002272065C75079739 @default.
• W2002272065 hasConceptScore W2002272065C75473681 @default.
• W2002272065 hasIssue "3-4" @default.
• W2002272065 hasLocation W20022720651 @default.
• W2002272065 hasOpenAccess W2002272065 @default.
• W2002272065 hasPrimaryLocation W20022720651 @default.
• W2002272065 hasRelatedWork W1544881075 @default.

• next