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- W2002290813 endingPage "140" @default.
- W2002290813 startingPage "133" @default.
- W2002290813 abstract "Asymmetric transfer hydrogenation (ATH) is frequently carried out in the azeotropic mixture of formic acid (F) and triethylamine (T), where the F/T molar ratio is 2.5. This study shows that the F/T ratio affects both the reduction rate and enantioselectivity, with the optimum ratio being 0.2 in the ATH of ketones with the Ru-TsDPEN catalyst. Under such conditions, a range of substrates have been reduced, affording high yields and good to excellent enantioselectivities. In comparison with the common azeotropic F-T system, the reduction is faster. This protocol improves both the classic azeotropic and the aqueous-formate system when using water-insoluble ketones." @default.
- W2002290813 created "2016-06-24" @default.
- W2002290813 creator A5060815622 @default.
- W2002290813 creator A5075108316 @default.
- W2002290813 creator A5078527783 @default.
- W2002290813 creator A5079262155 @default.
- W2002290813 date "2012-05-01" @default.
- W2002290813 modified "2023-10-18" @default.
- W2002290813 title "Varying the ratio of formic acid to triethylamine impacts on asymmetric transfer hydrogenation of ketones" @default.
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