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- W2002300971 abstract "Abstract From readily available di‐ O ‐isopropylidene‐ D ‐glucose, a D ‐ribofuranoid glycoaminoxy acid and its t Bu ester have been efficiently prepared as a new family of sugar building blocks by introducing the phthalimido aminoxy group by a Mitsunobu reaction. We found that the t Bu ester can be selectively deprotected with 13.7 % TFA in CH 2 Cl 2 at 0 °C in the presence of the 1,2‐ O ‐isopropylidene acetal. This selective deprotection has made possible the synthesis of homo‐oligomers of glycoaminoxy acids (up to six sugar units) as a novel type of oligosaccharide mimetics. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)" @default.
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- W2002300971 date "2009-11-11" @default.
- W2002300971 modified "2023-09-25" @default.
- W2002300971 title "Synthesis of Oligosaccharide Mimetics with Glycoaminoxy Acids" @default.
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- W2002300971 doi "https://doi.org/10.1002/ejoc.200900945" @default.
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