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- W2002306604 abstract "The transport parameters (permeability coefficients, separation factors) were determined for the separation of mixtures of n-butane and methane. The content of butane in the feed was in the range 3.7–7.9% and simulated the composition of associated petroleum gas. The experiments were carried out at room temperature and feed pressure of 2–6 atm. Novel membrane materials – poly(trimethylsilylnorbornene) and poly(bis-(trimethylsilyl)tricyclononene) – were studied in the form of dense films. Both polymers reveal a distinct solubility controlled permeation: the permeate streams were strongly enriched (up to 58%) with the heavier component (C4H10), the permeability of methane was reduced by a factor 3–4 as compared to the permeability of pure methane, and high permeability of butane was observed. Novel Si-containing poly(cycloolefins) as membrane materials were compared with high permeability polyacetylenes." @default.
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- W2002306604 date "2011-08-01" @default.
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- W2002306604 title "Solubility controlled permeation of hydrocarbons in novel highly permeable polymers" @default.
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- W2002306604 doi "https://doi.org/10.1016/j.memsci.2011.05.009" @default.
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