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- W2002309099 abstract "Auger electron spectroscopy (AES) was applied to study grain boundary and free surface equilibrium segregation under identical geometric, crystallographic and thermal conditions using specially prepared NiIn bicrystals with 0.8 and 1.2 at% In. Indium segregates slightly stronger to the grain boundaries than to the free surfaces. The segregation free energies were δG970Kmeg = 34±2 kJ/mol at the grain boundaries and ΔGIno = 3.05±0.5 kJ/mol at the surfaces. Attractive interaction between In and the trace element S was observed at the surfaces. It repels the trace elements B and C from the free surfaces, but not from the grain boundaries, which indicates that B and C would segregate stronger to the grain boundaries with In being absent. The characteristic behaviour of B, C, In and S at both types of interfaces was discussed with respect to their respective effect of grain boundary cohesion in Ni." @default.
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- W2002309099 date "1989-08-01" @default.
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- W2002309099 title "Surface and grain boundary segregation in NiIn studied under identical conditions with AES" @default.
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- W2002309099 doi "https://doi.org/10.1016/0169-4332(89)90503-5" @default.
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