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• W2002351971 abstract "A highly bulky methacrylate, tris(trimethylsilyl)silyl or supersilyl methacrylate, was polymerized quantitatively with 9-fluorenyllithium in the presence of (−)-sparteine as a chiral ligand in toluene at −78 °C to give insoluble polymers. The obtained polymers exhibited high isotacticity (mm>99%) and chirality, which was confirmed by diffuse reflectance circular dichroism spectroscopy. Thus, the bulky silyl methacrylate undergoes asymmetric anionic polymerization with the chiral initiating systems via formation of a prevailing one-handed helical conformation." @default.
• W2002351971 created "2016-06-24" @default.
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• W2002351971 date "2012-10-17" @default.
• W2002351971 modified "2023-10-17" @default.
• W2002351971 title "Asymmetric anionic polymerization of tris(trimethylsilyl)silyl methacrylate: a highly isotactic helical chiral polymer" @default.
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• W2002351971 doi "https://doi.org/10.1038/pj.2012.178" @default.
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