FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002364345> ?p ?o ?g. }

• W2002364345 endingPage "4062" @default.
• W2002364345 startingPage "4053" @default.
• W2002364345 abstract "The ligand 1,3-bis[3-(2-pyridyl)pyrazol-1-yl]propane (L8) has afforded six-coordinate monomeric and dimeric complexes [(L8)CoII(H2O)2][ClO4]2 (1), [(L8)NiII(MeCN)2][BPh4]2 (2), [(L8)NiII(O2CMe)][BPh4] (3), and [(L8)2Co2II(μ-O2CMe)2][BPh4]2(4). The crystal structures of 1, 2 · MeCN, 3, and 4 revealed that the ligand L8 is flexible enough to expand its coordinating ability by fine-tuning the angle between the chelating fragments and hence folds around cobalt(II)/nickel(II) centers to act as a tetradentate chelate, allowing additional coordination by two trans-H2O, cis-MeCN, and a bidentate acetate affording examples of distorted octahedral CoIIN2(pyridyl)N2′(pyrazole)O2(water), NiIIN2(pyridyl)N2′(pyrazole)N2″(acetonitrile), and NiIIN2(pyridyl)N2′(pyrazole)O2′(acetate) coordination. The angles between the two CoN2/NiN2 planes span a wide range 23.539(1)° (1), 76.934(8)° (2), and 69.874(14)° (3). In contrast, complex 4 is a bis-μ-1,3-acetato-bridged (syn–anti coordination mode) dicobalt(II) complex [Co⋯Co separation: 4.797(8) Å] in which L8 provides terminal bidentate pyridylpyrazole coordination to each cobalt(II) center. To our knowledge, this report provides first examples of such a coordination versatility of L8. Absorption spectral studies (MeCN solution) have been done for all the complexes. Complexes 1–3 are uniformly high-spin. Temperature-dependent (2–300 K) magnetic studies on 4 reveal weak ferromagnetic exchange coupling (H^=-JS1·S2) between two cobalt(II) (S = 3/2) ions. The best-fit parameters obtained are: Δ (axial splitting parameter) = −765(5) cm−1, λ (spin-orbit coupling) = −120(3) cm−1, k (orbital reduction factor) = 0.93, and J (magnetic exchange coupling constant) = +1.60(2) m−1." @default.
• W2002364345 created "2016-06-24" @default.
• W2002364345 creator A5041910204 @default.
• W2002364345 creator A5049061138 @default.
• W2002364345 creator A5069201232 @default.
• W2002364345 date "2006-09-01" @default.
• W2002364345 modified "2023-09-24" @default.
• W2002364345 title "Coordination versatility of 1,3-bis[3-(2-pyridyl)pyrazol-1-yl]propane: Co(II) and Ni(II) complexes" @default.
• W2002364345 cites W1577234663 @default.
• W2002364345 cites W1796661758 @default.
• W2002364345 cites W1939122629 @default.
• W2002364345 cites W1947248666 @default.
• W2002364345 cites W1963866364 @default.
• W2002364345 cites W1964649722 @default.
• W2002364345 cites W1964909614 @default.
• W2002364345 cites W1968051334 @default.
• W2002364345 cites W1972357040 @default.
• W2002364345 cites W1972579981 @default.
• W2002364345 cites W1974162253 @default.
• W2002364345 cites W1976069587 @default.
• W2002364345 cites W1976893889 @default.
• W2002364345 cites W1987590905 @default.
• W2002364345 cites W1990786847 @default.
• W2002364345 cites W1991243318 @default.
• W2002364345 cites W1994373927 @default.
• W2002364345 cites W1994962284 @default.
• W2002364345 cites W1996410305 @default.
• W2002364345 cites W1998722626 @default.
• W2002364345 cites W2002361865 @default.
• W2002364345 cites W2004534548 @default.
• W2002364345 cites W2006198497 @default.
• W2002364345 cites W2007338127 @default.
• W2002364345 cites W2008740698 @default.
• W2002364345 cites W2013660743 @default.
• W2002364345 cites W2018482312 @default.
• W2002364345 cites W2021416303 @default.
• W2002364345 cites W2026180730 @default.
• W2002364345 cites W2038131884 @default.
• W2002364345 cites W2038178800 @default.
• W2002364345 cites W2047414170 @default.
• W2002364345 cites W2048639761 @default.
• W2002364345 cites W2052053406 @default.
• W2002364345 cites W2053535968 @default.
• W2002364345 cites W2053636727 @default.
• W2002364345 cites W2058315837 @default.
• W2002364345 cites W2063560775 @default.
• W2002364345 cites W2064354662 @default.
• W2002364345 cites W2064895851 @default.
• W2002364345 cites W2066610499 @default.
• W2002364345 cites W2069130005 @default.
• W2002364345 cites W2069623452 @default.
• W2002364345 cites W2077206071 @default.
• W2002364345 cites W2081614862 @default.
• W2002364345 cites W2084669405 @default.
• W2002364345 cites W2085130352 @default.
• W2002364345 cites W2089795620 @default.
• W2002364345 cites W2099037802 @default.
• W2002364345 cites W2123978623 @default.
• W2002364345 cites W2142397199 @default.
• W2002364345 cites W2152079199 @default.
• W2002364345 cites W2154019687 @default.
• W2002364345 cites W2163068944 @default.
• W2002364345 cites W2163941502 @default.
• W2002364345 cites W2166689829 @default.
• W2002364345 cites W2319998213 @default.
• W2002364345 cites W51363676 @default.
• W2002364345 doi "https://doi.org/10.1016/j.ica.2006.05.005" @default.
• W2002364345 hasPublicationYear "2006" @default.
• W2002364345 type Work @default.
• W2002364345 sameAs 2002364345 @default.
• W2002364345 citedByCount "71" @default.
• W2002364345 countsByYear W20023643452012 @default.
• W2002364345 countsByYear W20023643452013 @default.
• W2002364345 countsByYear W20023643452014 @default.
• W2002364345 countsByYear W20023643452015 @default.
• W2002364345 countsByYear W20023643452016 @default.
• W2002364345 countsByYear W20023643452018 @default.
• W2002364345 countsByYear W20023643452019 @default.
• W2002364345 countsByYear W20023643452020 @default.
• W2002364345 countsByYear W20023643452021 @default.
• W2002364345 countsByYear W20023643452022 @default.
• W2002364345 countsByYear W20023643452023 @default.
• W2002364345 crossrefType "journal-article" @default.
• W2002364345 hasAuthorship W2002364345A5041910204 @default.
• W2002364345 hasAuthorship W2002364345A5049061138 @default.
• W2002364345 hasAuthorship W2002364345A5069201232 @default.
• W2002364345 hasConcept C11111787 @default.
• W2002364345 hasConcept C115624301 @default.
• W2002364345 hasConcept C116569031 @default.
• W2002364345 hasConcept C155647269 @default.
• W2002364345 hasConcept C170493617 @default.
• W2002364345 hasConcept C178516000 @default.
• W2002364345 hasConcept C178790620 @default.
• W2002364345 hasConcept C179104552 @default.
• W2002364345 hasConcept C185592680 @default.
• W2002364345 hasConcept C197404232 @default.
• W2002364345 hasConcept C198819137 @default.
• W2002364345 hasConcept C2776345496 @default.

• next