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- W2002400910 abstract "Reactions of atomic oxygen with isocyanic acid (HNCO) have been studied in incident and reflected shock wave experiments using HNCO/N2O/Ar mixtures. Quantitative time-histories of the NH(X3Σ−) and OH(X2Πi) radicals were measured behind the shock waves using cw, narrow-linewidth laser absorption at 336 nm and 307 nm, respectively. The second-order rate coefficients of the reactions: and were determined from early-time NH and OH formation rates, with least-squares two-parameter fits of the results given by: and cm3 mol−1 s−1. The minimum and maximum rate constant factors (ƒ,F) define the lower and upper uncertainty limits, respectively. An upper limit on the rate coefficient of was determined to be: ." @default.
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- W2002400910 date "1992-03-01" @default.
- W2002400910 modified "2023-09-27" @default.
- W2002400910 title "A shock tube study of reactions of atomic oxygen with isocyanic acid" @default.
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- W2002400910 doi "https://doi.org/10.1002/kin.550240306" @default.
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