Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002452008> ?p ?o ?g. }
- W2002452008 endingPage "4158" @default.
- W2002452008 startingPage "4147" @default.
- W2002452008 abstract "The 2,2‘-disubstituted 1,3-bis(diphenylphosphino)propane derivatives [XC(Me)(CH2PPh2)2] (X = 2-py, 1a; X = CH2OMe, 1b; X = Ph, 1c) and their corresponding palladium complexes [(P−P)PdCl2] (2a−c), [(P−P)Pd(OAc)2] (3a−c), [{2-methyl-2-pyridin-2-yl-1,3-bis(diphenylphosphino)propane}PdClMe] (4a), and [{(S)-(+)-N,N-dimethyl-α-methylbenzylamine-C,N}Pd{2-MeOCH2CMe(CH2PPh2)2}][ClO4] (5b) have been prepared and characterized. Palladium(II) complexes of 2-methyl-2-pyridin-2-yl-1,3-bis(diphenylphosphino)propane (1a) are highly active for the room-temperature copolymerization of ethene and carbon monoxide and, under our conditions, markedly more active than systems based on 1,3-bis(diphenylphosphino)propane (dppp), 1b and 1c. Catalysts formed from dppp, 1b, and 1c all show the expected increase in activity at elevated temperature (90 °C), while that formed from 1a is highly temperature-sensitive and rapidly decomposes." @default.
- W2002452008 created "2016-06-24" @default.
- W2002452008 creator A5003484293 @default.
- W2002452008 creator A5024866105 @default.
- W2002452008 creator A5058938001 @default.
- W2002452008 creator A5079202680 @default.
- W2002452008 creator A5091708807 @default.
- W2002452008 date "2002-09-01" @default.
- W2002452008 modified "2023-09-26" @default.
- W2002452008 title "Palladium Complexes of 2-Pyridin-2-yl Substituted 1,3-Bis(diphenylphosphino)propane: Highly Active Catalysts for the Room-Temperature Copolymerization of Carbon Monoxide with Ethene" @default.
- W2002452008 cites W1969836553 @default.
- W2002452008 cites W1970331629 @default.
- W2002452008 cites W1971214974 @default.
- W2002452008 cites W1974687075 @default.
- W2002452008 cites W1988785281 @default.
- W2002452008 cites W1989557333 @default.
- W2002452008 cites W1993436498 @default.
- W2002452008 cites W2004182290 @default.
- W2002452008 cites W2006208883 @default.
- W2002452008 cites W2006973236 @default.
- W2002452008 cites W2007603687 @default.
- W2002452008 cites W2008426816 @default.
- W2002452008 cites W2010332779 @default.
- W2002452008 cites W2011750122 @default.
- W2002452008 cites W2014666357 @default.
- W2002452008 cites W2014793017 @default.
- W2002452008 cites W2018537905 @default.
- W2002452008 cites W2018669316 @default.
- W2002452008 cites W2018856525 @default.
- W2002452008 cites W2019756091 @default.
- W2002452008 cites W2022872818 @default.
- W2002452008 cites W2024961781 @default.
- W2002452008 cites W2026451286 @default.
- W2002452008 cites W2028317888 @default.
- W2002452008 cites W2035894056 @default.
- W2002452008 cites W2037048025 @default.
- W2002452008 cites W2041691933 @default.
- W2002452008 cites W2042729583 @default.
- W2002452008 cites W2043980446 @default.
- W2002452008 cites W2049638026 @default.
- W2002452008 cites W2050713160 @default.
- W2002452008 cites W2051052884 @default.
- W2002452008 cites W2051941446 @default.
- W2002452008 cites W2059664137 @default.
- W2002452008 cites W2066652773 @default.
- W2002452008 cites W2068777897 @default.
- W2002452008 cites W2070284709 @default.
- W2002452008 cites W2071393248 @default.
- W2002452008 cites W2074498386 @default.
- W2002452008 cites W2074756034 @default.
- W2002452008 cites W2077037796 @default.
- W2002452008 cites W2085114769 @default.
- W2002452008 cites W2086677954 @default.
- W2002452008 cites W2088033404 @default.
- W2002452008 cites W2091928102 @default.
- W2002452008 cites W2099032988 @default.
- W2002452008 cites W2115224271 @default.
- W2002452008 cites W2124808520 @default.
- W2002452008 cites W2135476329 @default.
- W2002452008 cites W2150902436 @default.
- W2002452008 cites W2163616266 @default.
- W2002452008 cites W2318364212 @default.
- W2002452008 cites W2487763912 @default.
- W2002452008 cites W2921090447 @default.
- W2002452008 cites W2950765346 @default.
- W2002452008 doi "https://doi.org/10.1021/om020301c" @default.
- W2002452008 hasPublicationYear "2002" @default.
- W2002452008 type Work @default.
- W2002452008 sameAs 2002452008 @default.
- W2002452008 citedByCount "6" @default.
- W2002452008 countsByYear W20024520082016 @default.
- W2002452008 countsByYear W20024520082018 @default.
- W2002452008 crossrefType "journal-article" @default.
- W2002452008 hasAuthorship W2002452008A5003484293 @default.
- W2002452008 hasAuthorship W2002452008A5024866105 @default.
- W2002452008 hasAuthorship W2002452008A5058938001 @default.
- W2002452008 hasAuthorship W2002452008A5079202680 @default.
- W2002452008 hasAuthorship W2002452008A5091708807 @default.
- W2002452008 hasConcept C155647269 @default.
- W2002452008 hasConcept C15920480 @default.
- W2002452008 hasConcept C161790260 @default.
- W2002452008 hasConcept C168382676 @default.
- W2002452008 hasConcept C178790620 @default.
- W2002452008 hasConcept C179104552 @default.
- W2002452008 hasConcept C185592680 @default.
- W2002452008 hasConcept C188027245 @default.
- W2002452008 hasConcept C2776345496 @default.
- W2002452008 hasConcept C502130503 @default.
- W2002452008 hasConcept C512735826 @default.
- W2002452008 hasConcept C521977710 @default.
- W2002452008 hasConceptScore W2002452008C155647269 @default.
- W2002452008 hasConceptScore W2002452008C15920480 @default.
- W2002452008 hasConceptScore W2002452008C161790260 @default.
- W2002452008 hasConceptScore W2002452008C168382676 @default.
- W2002452008 hasConceptScore W2002452008C178790620 @default.
- W2002452008 hasConceptScore W2002452008C179104552 @default.
- W2002452008 hasConceptScore W2002452008C185592680 @default.
- W2002452008 hasConceptScore W2002452008C188027245 @default.