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- W2002477821 abstract "The optical constants of some imidazolium-based ionic liquids (ILs) are determined in the mid- and far-infrared regions by combining polarized attenuated total reflection (ATR) and transmittance spectra. The internal vibrations of the cations and anions and the interionic vibrations can thus be quantitatively evaluated. A comparison of the far-IR spectral response of several imidazolium derivatives associated with the (CF3SO2)2N− anion shows that methylation of the more acidic C(2)H imidazolium group does not change the far-IR intensity and hence that the CH···anion hydrogen bonds play a negligible role compared with electrostatic interactions. The calculated spectra of ion-pair dimers reproduce the far-IR density of states better than those of simple ion pairs." @default.
- W2002477821 created "2016-06-24" @default.
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- W2002477821 date "2010-05-14" @default.
- W2002477821 modified "2023-10-11" @default.
- W2002477821 title "Imidazolium-Based Ionic Liquids: Quantitative Aspects in the Far-Infrared Region" @default.
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- W2002477821 doi "https://doi.org/10.1021/jp102087m" @default.
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