Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002497461> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2002497461 endingPage "880" @default.
- W2002497461 startingPage "875" @default.
- W2002497461 abstract "The complexes [Rh(CO)LTp′] {L = CO or PPh3, Tp′ = hydrotris(3,5-dimethylpyrazolyl)borate} reacted with the ortho-quinone o-C6Cl4O2 (o-chloranil; 3,4,5,6-tetrachloro-1,2-benzoquinone) to give [Rh{C(O)OC6Cl4O}LTp′] (L = CO, 1; L = PPh3, 2). X-Ray structural studies on 2 reveal CO insertion into one Rh–O bond of a rhodium–catecholate ring. Loss of the inserted CO on UV irradiation (of 1) or thermolysis (of 2) gives [Rh(o-O2C6Cl4)LTp′] (L = CO 3 or PPh34); thermal substitution of the CO ligand of [Rh(o-O2C6Cl4)(CO)Tp′] with L provides a second route to [Rh(o-O2C6Cl4)(PPh3)Tp′] as well as [Rh(o-O2C6Cl4)LTp′] {L = AsPh35, P(OPh)36 or py 7} which are oxidised by [NO]+ to the monocations [Rh(o-O2C6Cl4)LTp′]+4++–7++. X-Ray structural studies on the redox pair [Rh(o-O2C6Cl4)(PPh3)Tp′]z (z = 0, 4 or 1, 4++) are consistent with catecholate ligand-based oxidation; the ESR spectra of the paramagnetic cations 4++–7++ suggest little delocalisation of unpaired electron density from the semiquinone ligand to the RhIIILTp′ unit." @default.
- W2002497461 created "2016-06-24" @default.
- W2002497461 creator A5003647050 @default.
- W2002497461 creator A5050781338 @default.
- W2002497461 creator A5051427929 @default.
- W2002497461 creator A5067288167 @default.
- W2002497461 creator A5075232878 @default.
- W2002497461 date "2001-01-01" @default.
- W2002497461 modified "2023-09-23" @default.
- W2002497461 title "Redox-active catecholate complexes of rhodium hydrotris(pyrazolyl)borates" @default.
- W2002497461 cites W1999197525 @default.
- W2002497461 cites W2010049864 @default.
- W2002497461 cites W2034141645 @default.
- W2002497461 cites W2047849100 @default.
- W2002497461 cites W2061428438 @default.
- W2002497461 cites W2148062424 @default.
- W2002497461 cites W3136772999 @default.
- W2002497461 doi "https://doi.org/10.1039/b010061g" @default.
- W2002497461 hasPublicationYear "2001" @default.
- W2002497461 type Work @default.
- W2002497461 sameAs 2002497461 @default.
- W2002497461 citedByCount "6" @default.
- W2002497461 crossrefType "journal-article" @default.
- W2002497461 hasAuthorship W2002497461A5003647050 @default.
- W2002497461 hasAuthorship W2002497461A5050781338 @default.
- W2002497461 hasAuthorship W2002497461A5051427929 @default.
- W2002497461 hasAuthorship W2002497461A5067288167 @default.
- W2002497461 hasAuthorship W2002497461A5075232878 @default.
- W2002497461 hasConcept C116569031 @default.
- W2002497461 hasConcept C155647269 @default.
- W2002497461 hasConcept C160434732 @default.
- W2002497461 hasConcept C161790260 @default.
- W2002497461 hasConcept C170493617 @default.
- W2002497461 hasConcept C178790620 @default.
- W2002497461 hasConcept C179104552 @default.
- W2002497461 hasConcept C185592680 @default.
- W2002497461 hasConcept C2776370595 @default.
- W2002497461 hasConcept C2780643102 @default.
- W2002497461 hasConcept C501308230 @default.
- W2002497461 hasConcept C521398313 @default.
- W2002497461 hasConcept C55493867 @default.
- W2002497461 hasConcept C55904794 @default.
- W2002497461 hasConcept C71240020 @default.
- W2002497461 hasConcept C75473681 @default.
- W2002497461 hasConcept C8010536 @default.
- W2002497461 hasConceptScore W2002497461C116569031 @default.
- W2002497461 hasConceptScore W2002497461C155647269 @default.
- W2002497461 hasConceptScore W2002497461C160434732 @default.
- W2002497461 hasConceptScore W2002497461C161790260 @default.
- W2002497461 hasConceptScore W2002497461C170493617 @default.
- W2002497461 hasConceptScore W2002497461C178790620 @default.
- W2002497461 hasConceptScore W2002497461C179104552 @default.
- W2002497461 hasConceptScore W2002497461C185592680 @default.
- W2002497461 hasConceptScore W2002497461C2776370595 @default.
- W2002497461 hasConceptScore W2002497461C2780643102 @default.
- W2002497461 hasConceptScore W2002497461C501308230 @default.
- W2002497461 hasConceptScore W2002497461C521398313 @default.
- W2002497461 hasConceptScore W2002497461C55493867 @default.
- W2002497461 hasConceptScore W2002497461C55904794 @default.
- W2002497461 hasConceptScore W2002497461C71240020 @default.
- W2002497461 hasConceptScore W2002497461C75473681 @default.
- W2002497461 hasConceptScore W2002497461C8010536 @default.
- W2002497461 hasIssue "6" @default.
- W2002497461 hasLocation W20024974611 @default.
- W2002497461 hasOpenAccess W2002497461 @default.
- W2002497461 hasPrimaryLocation W20024974611 @default.
- W2002497461 hasRelatedWork W1983162102 @default.
- W2002497461 hasRelatedWork W1985297581 @default.
- W2002497461 hasRelatedWork W2042222153 @default.
- W2002497461 hasRelatedWork W2044585969 @default.
- W2002497461 hasRelatedWork W2052207184 @default.
- W2002497461 hasRelatedWork W2154612735 @default.
- W2002497461 hasRelatedWork W2316891600 @default.
- W2002497461 hasRelatedWork W2886352771 @default.
- W2002497461 hasRelatedWork W4235533786 @default.
- W2002497461 hasRelatedWork W4240940140 @default.
- W2002497461 isParatext "false" @default.
- W2002497461 isRetracted "false" @default.
- W2002497461 magId "2002497461" @default.
- W2002497461 workType "article" @default.