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• W2002581292 abstract "The electrochemical properties of palladium adlayers on Au(1 1 1) are compared with those of massive Pd(1 1 1). Electro-deposited Pd forms a pseudomorphic overlayer on the unreconstructed Au(1 1 1) surface following the stacking sequence of the substrate. The altered electrochemical behaviour of the overlayer can be ascribed to changes in the electronic structure due to lateral strain. A gradual change to bulk properties is observed with increasing Pd coverage. Besides hydrogen adsorption, sulphate adsorption and surface oxidation, formic acid oxidation was chosen as a test reaction. The influence of lateral strain on the reaction kinetics of formic acid oxidation is discussed." @default.
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• W2002581292 date "2003-05-01" @default.
• W2002581292 modified "2023-09-26" @default.
• W2002581292 title "Electrochemical behaviour of pseudomorphic overlayers: Pd on Au(1 1 1)" @default.
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• W2002581292 doi "https://doi.org/10.1016/s1381-1169(03)00018-9" @default.
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