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• W2002606229 abstract "A series of symmetrical and unsymmetrical azoalkanes were synthesized and their potential as a free-radical source for rheology modification of polyolefins was investigated. The experimental results show that unsymmetrical azoalkanes, in particular N-cyclohexyl-N'-tert-octyldiazene (13), can be successfully used for manufacturing controlled-rheology poly(propylene) and cross-linked high-density polyethylene. For example, the melt flow rate of a general-purpose poly(propylene) (MFR = 14) could be increased to a value of 800 when 0.75 wt.-% of azoalkane 13 was added during reactive processing. In parallel, it was found that 13 has a remarkable efficiency for free-radical-induced cross-linking of high-density polyethylene, resulting in similar gel contents to dicumyl peroxide." @default.
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• W2002606229 date "2007-06-11" @default.
• W2002606229 modified "2023-10-17" @default.
• W2002606229 title "Azoalkanes: A Novel Class of Additives for Cross-Linking and Controlled Degradation of Polyolefins" @default.
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• W2002606229 doi "https://doi.org/10.1002/mame.200600498" @default.
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