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- W2002609777 abstract "Lower cyclic oligomers C2–C5 of a family of naphthalenophane formaldehyde acetals Cn have been isolated and characterized, the dimer being obtained in two atropisomeric forms, syn-C2 and anti-C2, as confirmed by X-ray analysis. The investigated cyclophanes showed interesting recognition properties towards electron-poor guests (K≈105 M−1 for association of the guanidinium ion with C3 in chloroform). A library of macrocycles was generated by acid catalyzed transacetalation of Cn in chloroform, but the dynamic nature of the system was spoiled by the occurrence of irreversible reaction pathways promoted by the relatively easy formation of extended benzyl-like carbocations I." @default.
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- W2002609777 date "2013-04-01" @default.
- W2002609777 modified "2023-09-28" @default.
- W2002609777 title "Naphthalenophane formaldehyde acetals as candidate structures for the generation of dynamic libraries via transacetalation processes" @default.
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- W2002609777 doi "https://doi.org/10.1016/j.tet.2013.01.080" @default.
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