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- W2002619853 abstract "The rate of solvolysis of 1-phenylethyl chloride has been followed both polarimetrically and titrimetrically in 60% and in 70% dioxan. The polarimetric rate exceeds the titrimetric rate, and the extent of racemisation decreases slightly with increasing water-content of the medium. The effects of added salts (LiCIO4, NEt4CIO4, LiCl, and in less detail NaOH, and LiBr) have been examined; these results confirm the conclusion to be drawn from the discrepancy between the polarimetric and titrimetric rate coefficients, namely that ion-pair intermediates are involved in this reaction. They suggest also that the first stage of solvolysis is slightly reversed by added chloride ions. The exchange of radiochloride into the organic chloride has also been examined, and is consistent with the above conclusion. The possibility that styrene is an intermediate significant in these solvolyses has been excluded." @default.
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- W2002619853 date "2010-09-02" @default.
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- W2002619853 title "Some aspects of the solvolysis of 1-phenylethyl chloride" @default.
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- W2002619853 doi "https://doi.org/10.1002/recl.19680871209" @default.
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