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- W2002635251 abstract "Clusters of magnesium and dimethyl ether (CH3OCH3) have been prepared in a supersonic expansion pick-up source. Solvated ions Mg+(dimethyl ether)n have been observed for n=2 and higher. Surprisingly, the single-photon ionisation process is very inefficient to form these clusters. Reaction products have been found to arise from an ion-molecule reaction where Mg+ (3s 2S) attacks the methyl oxygen bond in dimethyl ether. This reaction is made possible by addition of solvent molecules in the cluster, and the products are found with a maximum population when solvated by four molecules. This process, already observed in collisions of similar clusters and magnesium ions, is manifest here as an intracluster reaction." @default.
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- W2002635251 date "2000-09-01" @default.
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- W2002635251 title "Intracluster reactions of singly ionised magnesium atoms with dimethyl ether" @default.
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- W2002635251 doi "https://doi.org/10.1016/s0009-2614(00)00835-6" @default.
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