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- W2002757485 abstract "Abstract The complexation of L-aspartic acid by a series of mixed-ligand Tb(III) complexes has been studied by means of circularly polarized luminescence (CPL) spectroscopy. In several Tb(TDL) 2 (ASP) and Tb(MDL)(ASP) complexes (TDL = terdentate ligand, and MDL = multidentate ligand), it was established that the L-ASP ligand bound in a bidentate manner between the two carboxyl groups. However, the resulting CPL spectra were found to be vastly different in the two series of compounds, an effect whose origin probably lies in different ASP conformations in the mixed-ligand complexes. A systematic variation of the concentration of L-ASP enabled calculation of the formation constants associated with binding of this ligand by Tb(TDL) − 2 and Tb(MDL) − . The bindings of L-ASP by the Tb(MDL) series is more facile than that of the Tb(TDL) 2 series, but in all cases the formation constants are greatly reduced from the analogous value known for Tb(ASP)." @default.
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- W2002757485 date "1983-01-01" @default.
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- W2002757485 title "Solution chemistry of lanthanide complexes.5. Circularly polarized luminescence studies on Tb(III) mixed-ligand complexes containing L-aspartic acid" @default.
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- W2002757485 doi "https://doi.org/10.1016/s0020-1693(00)82784-x" @default.
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