Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002783443> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W2002783443 endingPage "342" @default.
- W2002783443 startingPage "319" @default.
- W2002783443 abstract "The disappearance of individual sulfur compounds has been investigated during the hydrotreatment (simultaneous removal of sulfur, nitrogen and oxygen) of coal-derived naphtha over each of the bulk second row transition metal sulfides. The sulfur compounds in the naphtha mainly consist of thiols/sulfides, thiophene and substituted thiophenes. Thiols/sulfides are, in general, more easily converted than thiophenic compounds are. Lighter thiols/sulfides are intermediates in the conversion of higher boiling thiols/sulfides or thiophenes. Side chain alkyl CC bond breaking is predominant during the disappearance of thiophenes over the Zr and Nb catalysts while CS bond breaking is predominant over the other catalysts. Thiophenic compounds are hydrogenated prior to desulfurization over the Mo, Ru, Rh and Pd sulfides. Highly substituted thiophenes are the compounds most difficult to convert over the Mo, Ru, Rh and Pd sulfides. The substituted thiophenes exhibit different reactivity trends over molybdenum sulfide, on one hand, and the Group VIII sulfides, on the other, indicating different adsorption modes and surface mechanisms for their conversion over these catalysts. Individual sulfur compounds do not follow first order kinetics and the disappearance rate is limited by product inhibition. The overall removal of sulfur does not follow simple first or second order kinetics since the individual compounds do not react in parallel, independent or first order reactions." @default.
- W2002783443 created "2016-06-24" @default.
- W2002783443 creator A5005301084 @default.
- W2002783443 creator A5019529061 @default.
- W2002783443 creator A5089274817 @default.
- W2002783443 date "1997-03-01" @default.
- W2002783443 modified "2023-09-26" @default.
- W2002783443 title "Second row transition metal sulfides for the hydrotreatment of coal-derived naphtha II. Removal of individual sulfur compounds" @default.
- W2002783443 cites W152757273 @default.
- W2002783443 cites W1977655936 @default.
- W2002783443 cites W1979375467 @default.
- W2002783443 cites W1983503853 @default.
- W2002783443 cites W1987700725 @default.
- W2002783443 cites W1987975690 @default.
- W2002783443 cites W1990951173 @default.
- W2002783443 cites W1996608507 @default.
- W2002783443 cites W2003229305 @default.
- W2002783443 cites W2026553452 @default.
- W2002783443 cites W2033194614 @default.
- W2002783443 cites W2034763371 @default.
- W2002783443 cites W2038489341 @default.
- W2002783443 cites W2045577617 @default.
- W2002783443 cites W2051411707 @default.
- W2002783443 cites W2066422775 @default.
- W2002783443 cites W2075941024 @default.
- W2002783443 cites W2332711238 @default.
- W2002783443 cites W2507773975 @default.
- W2002783443 cites W4242750002 @default.
- W2002783443 cites W82154715 @default.
- W2002783443 doi "https://doi.org/10.1016/s0926-860x(96)00318-3" @default.
- W2002783443 hasPublicationYear "1997" @default.
- W2002783443 type Work @default.
- W2002783443 sameAs 2002783443 @default.
- W2002783443 citedByCount "25" @default.
- W2002783443 countsByYear W20027834432012 @default.
- W2002783443 countsByYear W20027834432015 @default.
- W2002783443 countsByYear W20027834432019 @default.
- W2002783443 countsByYear W20027834432020 @default.
- W2002783443 crossrefType "journal-article" @default.
- W2002783443 hasAuthorship W2002783443A5005301084 @default.
- W2002783443 hasAuthorship W2002783443A5019529061 @default.
- W2002783443 hasAuthorship W2002783443A5089274817 @default.
- W2002783443 hasConcept C106773901 @default.
- W2002783443 hasConcept C134484671 @default.
- W2002783443 hasConcept C161790260 @default.
- W2002783443 hasConcept C178790620 @default.
- W2002783443 hasConcept C179104552 @default.
- W2002783443 hasConcept C185592680 @default.
- W2002783443 hasConcept C197129369 @default.
- W2002783443 hasConcept C2778480967 @default.
- W2002783443 hasConcept C2779953032 @default.
- W2002783443 hasConcept C2780263894 @default.
- W2002783443 hasConcept C2780596425 @default.
- W2002783443 hasConcept C518881349 @default.
- W2002783443 hasConcept C549387045 @default.
- W2002783443 hasConcept C68000547 @default.
- W2002783443 hasConceptScore W2002783443C106773901 @default.
- W2002783443 hasConceptScore W2002783443C134484671 @default.
- W2002783443 hasConceptScore W2002783443C161790260 @default.
- W2002783443 hasConceptScore W2002783443C178790620 @default.
- W2002783443 hasConceptScore W2002783443C179104552 @default.
- W2002783443 hasConceptScore W2002783443C185592680 @default.
- W2002783443 hasConceptScore W2002783443C197129369 @default.
- W2002783443 hasConceptScore W2002783443C2778480967 @default.
- W2002783443 hasConceptScore W2002783443C2779953032 @default.
- W2002783443 hasConceptScore W2002783443C2780263894 @default.
- W2002783443 hasConceptScore W2002783443C2780596425 @default.
- W2002783443 hasConceptScore W2002783443C518881349 @default.
- W2002783443 hasConceptScore W2002783443C549387045 @default.
- W2002783443 hasConceptScore W2002783443C68000547 @default.
- W2002783443 hasIssue "2" @default.
- W2002783443 hasLocation W20027834431 @default.
- W2002783443 hasOpenAccess W2002783443 @default.
- W2002783443 hasPrimaryLocation W20027834431 @default.
- W2002783443 hasRelatedWork W1986098115 @default.
- W2002783443 hasRelatedWork W1997647091 @default.
- W2002783443 hasRelatedWork W2002783443 @default.
- W2002783443 hasRelatedWork W2023272789 @default.
- W2002783443 hasRelatedWork W2043911919 @default.
- W2002783443 hasRelatedWork W2052937719 @default.
- W2002783443 hasRelatedWork W2055254625 @default.
- W2002783443 hasRelatedWork W2141907913 @default.
- W2002783443 hasRelatedWork W2552038845 @default.
- W2002783443 hasRelatedWork W3119134169 @default.
- W2002783443 hasVolume "150" @default.
- W2002783443 isParatext "false" @default.
- W2002783443 isRetracted "false" @default.
- W2002783443 magId "2002783443" @default.
- W2002783443 workType "article" @default.