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- W2002803795 abstract "A lattice dynamics calculation of the carbonyl sulphide crystal has been made using an atom-atom potential in the rigid body approximation. The phonon sideband of the intramolecular bending mode is discussed and compared with the phonon density of states. An intensity weighted density of states is obtained by calculation of the transition dipole moments from the ground state to two-phonon states of the type vibrational exciton + lattice phonon by expansion of the dipole operator to second order. It is shown that the bulk of intensity in the phonon sideband is borrowed by anharmonic coupling from the free exciton band. The anharmonic coupling is treated in a simplified way by a perturbation method." @default.
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- W2002803795 title "Lattice dynamics and phonon sidebands of vibrational excitons in carbonyl sulphide crystal" @default.
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- W2002803795 doi "https://doi.org/10.1088/0022-3719/10/1/006" @default.
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