FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2002814458> ?p ?o ?g. }

• W2002814458 endingPage "11060" @default.
• W2002814458 startingPage "11052" @default.
• W2002814458 abstract "Decene and acetone were hydrogenated over Ni, Pd, Pt, Cu, Ag, and Au catalysts in a polymer electrolyte hydrogen pump (PEHP) reactor. Water was oxidized over a Pt mesh anode and protons were pumped to the catalysts supported on porous carbon cathodes in contact with an organic liquid phase. The protons are reduced at the cathode to adsorbed hydrogen atoms which hydrogenate adsorbed olefins and carbonyl groups by heterogeneous catalysis. At low current density decene hydrogenation over Pd and Pt increased with the current density to the 1/2 power, indicating the surface reaction of adsorbed hydrogen with adsorbed decene was the rate limiting step. At high current density the reaction rate decreased linearly with current density, indicating adsorbed hydrogen inhibited decene adsorption and decene adsorption was the rate limiting step. Decene hydrogenation at 50 °C was 100 times slower over Ni, Cu, Ag, and Au catalysts compared to Pd and Pt. Acetone hydrogenation over Pt increased linearly with proton current density and was 10 times slower than decene hydrogenation. Acetone and decene hydrogenation rates at 50 °C were almost the same over Cu catalysts. Data were fit with modified Langmuir−Hinshelwood kinetics; the rate limiting steps were identified as the first hydrogen addition to adsorbed decene and the second hydrogen addition to adsorbed acetone." @default.
• W2002814458 created "2016-06-24" @default.
• W2002814458 creator A5005903614 @default.
• W2002814458 creator A5032094470 @default.
• W2002814458 date "2010-06-11" @default.
• W2002814458 modified "2023-10-17" @default.
• W2002814458 title "A Polymer Electrolyte Hydrogen Pump Hydrogenation Reactor" @default.
• W2002814458 cites W1983912440 @default.
• W2002814458 cites W1986631321 @default.
• W2002814458 cites W1993629745 @default.
• W2002814458 cites W2001991341 @default.
• W2002814458 cites W2003749809 @default.
• W2002814458 cites W2013449860 @default.
• W2002814458 cites W2016569243 @default.
• W2002814458 cites W2023141039 @default.
• W2002814458 cites W2024621797 @default.
• W2002814458 cites W2024683043 @default.
• W2002814458 cites W2032723423 @default.
• W2002814458 cites W2034797498 @default.
• W2002814458 cites W2049010859 @default.
• W2002814458 cites W2052082329 @default.
• W2002814458 cites W2052202097 @default.
• W2002814458 cites W2056222859 @default.
• W2002814458 cites W2056651013 @default.
• W2002814458 cites W2065543003 @default.
• W2002814458 cites W2080814637 @default.
• W2002814458 cites W2082742163 @default.
• W2002814458 cites W2085374864 @default.
• W2002814458 cites W2092136876 @default.
• W2002814458 cites W2092712297 @default.
• W2002814458 cites W2139471708 @default.
• W2002814458 cites W2155875435 @default.
• W2002814458 cites W2158953298 @default.
• W2002814458 cites W2168810403 @default.
• W2002814458 cites W2496933785 @default.
• W2002814458 cites W31715198 @default.
• W2002814458 cites W61242825 @default.
• W2002814458 doi "https://doi.org/10.1021/ie100631a" @default.
• W2002814458 hasPublicationYear "2010" @default.
• W2002814458 type Work @default.
• W2002814458 sameAs 2002814458 @default.
• W2002814458 citedByCount "32" @default.
• W2002814458 countsByYear W20028144582012 @default.
• W2002814458 countsByYear W20028144582013 @default.
• W2002814458 countsByYear W20028144582014 @default.
• W2002814458 countsByYear W20028144582015 @default.
• W2002814458 countsByYear W20028144582016 @default.
• W2002814458 countsByYear W20028144582017 @default.
• W2002814458 countsByYear W20028144582018 @default.
• W2002814458 countsByYear W20028144582019 @default.
• W2002814458 countsByYear W20028144582020 @default.
• W2002814458 countsByYear W20028144582021 @default.
• W2002814458 countsByYear W20028144582022 @default.
• W2002814458 countsByYear W20028144582023 @default.
• W2002814458 crossrefType "journal-article" @default.
• W2002814458 hasAuthorship W2002814458A5005903614 @default.
• W2002814458 hasAuthorship W2002814458A5032094470 @default.
• W2002814458 hasConcept C147789679 @default.
• W2002814458 hasConcept C150394285 @default.
• W2002814458 hasConcept C161790260 @default.
• W2002814458 hasConcept C17525397 @default.
• W2002814458 hasConcept C178790620 @default.
• W2002814458 hasConcept C179104552 @default.
• W2002814458 hasConcept C185592680 @default.
• W2002814458 hasConcept C190463131 @default.
• W2002814458 hasConcept C2781213060 @default.
• W2002814458 hasConcept C512968161 @default.
• W2002814458 hasConcept C52859227 @default.
• W2002814458 hasConcept C57156300 @default.
• W2002814458 hasConcept C68801617 @default.
• W2002814458 hasConceptScore W2002814458C147789679 @default.
• W2002814458 hasConceptScore W2002814458C150394285 @default.
• W2002814458 hasConceptScore W2002814458C161790260 @default.
• W2002814458 hasConceptScore W2002814458C17525397 @default.
• W2002814458 hasConceptScore W2002814458C178790620 @default.
• W2002814458 hasConceptScore W2002814458C179104552 @default.
• W2002814458 hasConceptScore W2002814458C185592680 @default.
• W2002814458 hasConceptScore W2002814458C190463131 @default.
• W2002814458 hasConceptScore W2002814458C2781213060 @default.
• W2002814458 hasConceptScore W2002814458C512968161 @default.
• W2002814458 hasConceptScore W2002814458C52859227 @default.
• W2002814458 hasConceptScore W2002814458C57156300 @default.
• W2002814458 hasConceptScore W2002814458C68801617 @default.
• W2002814458 hasIssue "21" @default.
• W2002814458 hasLocation W20028144581 @default.
• W2002814458 hasOpenAccess W2002814458 @default.
• W2002814458 hasPrimaryLocation W20028144581 @default.
• W2002814458 hasRelatedWork W2021781456 @default.
• W2002814458 hasRelatedWork W2042038334 @default.
• W2002814458 hasRelatedWork W2096926741 @default.
• W2002814458 hasRelatedWork W2587601747 @default.
• W2002814458 hasRelatedWork W2949708076 @default.
• W2002814458 hasRelatedWork W3092753321 @default.
• W2002814458 hasRelatedWork W3094803157 @default.
• W2002814458 hasRelatedWork W3146233206 @default.
• W2002814458 hasRelatedWork W4367672340 @default.
• W2002814458 hasRelatedWork W4382701215 @default.
• W2002814458 hasVolume "49" @default.

• next