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- W2002820661 abstract "Three in one: The exocyclic β-bromo enol ether is a synthetically useful functional moiety in the preparation of functionalized oxygen heterocycles. A new tandem method for the synthesis of this valuable moiety has been achieved by employing silyl-protected acetylenic alcohols. To demonstrate the synthetic potential of the developed method, a brief total synthesis of pachastrissamine was successfully attempted. NBS=N-bromosuccinimide. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2002820661 date "2011-04-27" @default.
- W2002820661 modified "2023-09-25" @default.
- W2002820661 title "Silver-Mediated exo-Selective Tandem Desilylative Bromination/Oxycyclization of Silyl-Protected Alkynes: Synthesis of 2-Bromomethylene-Tetrahydrofuran" @default.
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- W2002820661 doi "https://doi.org/10.1002/asia.201100158" @default.
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