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- W2002827762 abstract "Abstract The compounds 4,4′-bipyridinium nitrate trinitratodioxo-uranium(VI) [UO2(NO3)3][4,4′-bipyH]·HNO3 (1) and 4,4′-dipyridinium diaqua hexanitrato-thorate(IV) [Th(NO3)6][4,4′-bipyH2]·2H2O (2) were prepared and characterized. Their crystal structures have been determined using X-ray diffraction techniques. Both complexes crystallize in the monoclinic system with space groups P21/c for 1 and C2/c for 2. The geometry of the anion in 1 is a distorted hexagonal bipyrimidial coordination, while that in 2 is a distorted icosahedron. The cation in 1 is formed from hydrogen-bonded monoprotonated bipyridyl with a neutral nitrate molecule, whereas the cation in 2 is formed from hydrogen-bonded diprotonated bipyridyl with a water molecule. The cations in both complexes are connected with the anions through hydrogen bonds via the nitrate molecule in 1 and the water molecule in 2." @default.
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- W2002827762 date "1994-08-01" @default.
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- W2002827762 title "Preparation, characterization and crystal structure of 4,4′-bipyridinium nitrate trinitratodioxo-uranium(VI) and 4,4′-dipyridinium diaqua hexanitrato-thorate(IV)" @default.
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- W2002827762 doi "https://doi.org/10.1016/0925-8388(94)90156-2" @default.
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